提高金属涂层与有机基材附着力的表面改性研究-本原扫描探针.PDFVIP

提高金属涂层与有机基材附着力的表面改性研究 霍纯青，桑利军，陈强*，岳蕾，付亚波 北京印刷学院印刷包装材料与技术北京市重点实验室，北京大兴，102600 摘要 利用等离子体技术在有机玻璃(亚克力版)上完成金属铝的膜层制备，进行了膜层表面 的光泽度、附着力和耐腐蚀性等研究。实验发现采用磁控溅射制备的金属Al膜的光泽度非常好， 镀层为镜面光洁。而为了提高耐腐蚀性，在金属膜上镀了一层硅薄膜，结果对Al膜的光泽度没有 影响。同时，根据国家标准，在配制10％的NaOH溶液中进行耐腐蚀性测试，结果表明铝膜表面 没有任何被腐蚀的现象产生，薄膜耐腐蚀性能良好。但是金属薄膜在有机基材上的附着力较差， 为此进行了利用Ar 、O2等离子体对有机玻璃表面进行清洗，其目的一是对表面进行清洗，以除去 其表面附着的杂质污染物；其次等离子体轰击使表面变得更粗糙，有利于提高其对金属膜的附着 n 力；此外在薄膜表面添加过渡层，即在镀膜之前先在基材上镀一层其他材料，然后再镀金属膜。 c . 实验发现环氧材料和SiO2作为过渡层，薄膜的附着力显著提高。 关键词 等离子体应用；磁控溅射；附着力 m The study of adhesive between Al layer on PMMA surface by plasma treatment o c ABSTRACT: Using magnetron sputtering reactor technology metal coatings such as Al was deposited . on the surface of PMMA. In this process, we have explored the brightness, anti-corrosion and adhesion m of the Al coatings. It is found that the film is very brightness as a mirror. The nano-scale deposited p silicon oxide layer on Al surface for anti-corrosion propose did not decay the brightness. The s anti-corrosion experiment, by the national standard of immersion in 10% NaOH solution for 1min, . demonstrated no corrosive phenomena. However, the adhesion between metal coating and PMMA is w relatively small. So lots of works were done for this propose. Firstly, we used Ar and O2 plasma to clean w PMMA surface, in which plasma can clean and remove the impurity f