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SYMMETRY IN BONDING AND SPECTRA Willkommen结合和谱中的对称性.pdf
SYMMETRY
IN BONDING AND SPECTRA
AN INTRODUCTION
BODIE E. DOUGLAS
and
CHARLES A. HOLLINGSWORTH
Department of Chemistry
University of Pittsburgh
Pittsburgh, Pennsylvania
ACADEMIC PRESS , INC .
Harcourt Brace Jovanovich, Publishers
San Diego New York Boston
London Sydney Tokyo Toronto
Contents
Preface xi
The Importance of Symmetry in Chemistry
1.1 Symmetry in Nature 1
1.2 Electron Clouds in Atoms and Molecules 2
1.3 Spectroscopy , 4
1.4 Symmetry Rules for Chemical Reactions 5
1.5 Group Theory 5
1.6 Symmetry Groups and Symmetry Species 6
2 Properties of Groups
2. 1 Definition 9
2.2 Group Multiplication Tables 10
2.3 Group Generators and Their Relations 16
2.4 Permutation Groups 17
2.5 Conjugate Classes 18
2.6 Subgroups 19
2.7 Point Groups 2 1
2.8 Assigning Molecules to Point Groups
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