la-mn-o钙钛矿催化剂成分对nox和碳烟同时催化去除的影响.pdfVIP

20 5 No.5 Vol.20 2006 10 Journal of Chemical Engineering of Chinese Universities Oct. 2006 1003-9015(2006)05-0831-06 La-Mn-O NOx , , , ( , 200030) La-Mn-O (TPR) NOx CeK Cu La-Mn-O Ce K LaMnO3 LaCu La0.8K0.2MnO3 Mn La0.8K0.2Cu0.05Mn0.95O3 NO N2 66.0%290 NOx X701.7 O643.361 A Influence of Composition of Perovskite-type Catalysts La A B Mn O on 1-x x y 1-y 3 Simultaneous Removal of NO and Soot x PENG Xiao-sheng, LIN He, HUANG Zhen, SHANGGUAN Wen-feng (Center for Combustion and Environmental Technology, Shanghai Jiaotong University, Shanghai 200030, China) Abstract: Using temperature programmed reaction (TPR) method, catalytic removal of nitrogen oxides (NOx) and soot with modeled diesel engine exhaust was studied to investigate the effects of different catalysts. The catalysts used in this study are based on perovskite-type oxides LaMnO3. By substituting parts of La and Mn with other cations, La A B Mn O (A and B are dopants) were obtained and the catalytic activities of these 1-x x y 1-y 3 catalysts were systematically studied. The results indicate that both the selectivity and the activity of catalysts can be improved by doping appropriate cations. By substituting suitable amount of La with Ce or K, the performances of catalysts can be improved. Substituting parts of Mn with Cu at the same time, the performances of catalysts can be improved furthermore. The results show that the comprehensive performance of La K Cu Mn O is better than others.