右旋泛酸钠的波谱数据和结构分析.pdfVIP

30 5 ( ) Vol. 30 No. 5 2006 9 Jour nal of Hebei Normal Univer it y ( N atural Science Edition) Sep. 2006 右旋泛酸钠的波谱数据和结构分析 1 1 2 门永彪 , 郑学忠, 刘 河 ( 1. , 050016; 2. , 100850) 1 : ( IR) ( FA B M S) ( H NM R) 1 1 ( H HCOSY) N OE , . : ; 1H 1HCOSY ; NOE : O 621. 15 : A : 1000-5854( 2006) 05-0570-03 ( D ( + ) odium pantothenate, 1) / B 0 , , A . ( ) , B ( ) . [ 1~ 4] , . , 1 1 1 ( IR) ( FAB MS) ( HNM R) ( H H COSY) [ 5] [ 6] NOE , , . 1 1 CH3 1. 1 仪器和测定条件 9 6 4 3 HOCH2 C CH CON HCH CH COONa 2 2 RY 1( , 5 7 H3C OH ) ; PE 243B ( , D 589 2 8 nm, 25 e ) ; Nicolet 550 ( Nicolet 1 1 1 1 , KBr ) ; N SIM S Gly ( Water , FAB) ; H NM R H HCOSY NOE 1 HNMR JNM ECA 400C ( JEOL ) , D O CD SOCD . 2 3 3 1. 2 样品及对照品 . , , . 2 2. 1 纯度测定 , 2000 VD , , 99. 51 % . 2. 2 理化常数 169~ 172 e ( 168~ 170 e ) . 25 e + 27. 1b, 2000 + 25b~ + 27. 5b. * :2005 03 11; : 2005 07 18 :( D