Conductivities in stabilized Zirconia氧化钇稳定的氧化锆（YSZ）-课件PPT.ppt

Conductivities in stabilized Zirconia Intrinsic Ionic Disorder Frenkel Disorder Schottky Disorder Concentration of intrinsic defects Rocksalt structure type, NaCl and MgO 2. ZrO2相图 Temperature dependence of 12ScSZ YSZ相图 问题 ScSZ相图 CaF2结构 3. Defects in calcium stabilized zirconia CaSZ的晶格常数的计算 CaSZ密度的计算和测量 Density change in CaO-ZrO2 quenched from 1600oC Density change in CaO-ZrO2 quenched from 1800oC 4. Ion conducting in stabilized zirconia 1000oC时ZrO2-M2O3的最大导电率、导电率最大时M2O3含量与M3+离子半径的关系 导电活化能与哪些因素有关？ Defect association YSZ as example ScSZ as example The enthalpy ScSZ and YSZ Conductivities of ZrO2 systems at phase transformation Conductivity of YSZ as a function of oxygen partial pressure The bulk conductivity of microcrystalline ZrO2:14% Sc The conductivity of nanocrystalline ScSZ thin films 5. Defect Pair Model In YSZ Therefore Conductivity at low oxygen partial pressure Conductivity of nano ScSZ 6. Conductivity of nano YSZ Conductivity as a function of film thickness The nano YSZ conductivity Temperature dependence of YSZ films Microstructure Possible microstructure 7. Conductivity degradation of YSZ XRD analyses Results XRD hints STEM analyses Neutron diffraction Conductivity degradation of ScSZ Cubic fluorite at high temperature and rhombohedral pyrochlore at the low for SC2O3 contents 11% Change of electrical conductivity against Raman scattering intensity ratio I260 /I640 at 260 cm-1 and at 640 cm-1 Partial transformation of 10ScSZ electrolyte after annealing Conclusions The XRD lines of the annealed specimens were shifted by 2?=1o from their original position. Diffraction patterns of 8YSZ electrolytes show a decrease in the intensity of the XRD lines of about 50% after annealing, compared to that of the as-prepared electrolyte. The intensity decrease of the cubic phase lines in the annealed 8YSZ specimen is coupled with a broadening of the lines, so that the area of the lines of the annealed 8YSZ specimen is the same as that of the as-prepared specimen. No