螺环原酸酯之紫外光聚合反应研究-台湾科技大学.PDFVIP

螺環原酸酯之紫外光聚合反應研究 NSC 94-2216-E-011-006 萬彥昇、鍾曜暘、許應舉 * 國立台灣科技大學高分子工研究所 Fax: 02 E-mail: M9404402@mail.ntust.edu.tw Abstract 2.實驗 Spiro-orthoester (SOEs), the expanding monomers, 2-allyloxymethyl-1,4,6–trioxaspiro[4,4]nonane (ATN), 2.1.材料 2-phenoxymethyl-1,4,6-trioxa-Spiro-(4,4)-nonane (PTN) and 2,2-bis(1,4,6-trioxa-spiro-[4,4]-nonan-2-methyloxyphenyl)- 本研究合共成三種 SOE(spiro orthoesters) ，包含ATN(2- propane (BTP) were synthesized. They did not undergo any allyloxymethyl -1,4,6 –trioxaspiro [4,4] dec ane) 、PTN(2-Phen reaction when were heated at high temperature in the oxymethyl-1,4,6-trioxa-Spiro-(4,4)-nonane)及 BTP(2,2-Bis(1,4 presence of a photoinitiator-diaryliodonium salt (DAI). ,6-trioxa-spiro-[4,4]-nonan-2-methyloxyphenyl)-propane)並分 However, the photo-initiator containing SOEs underwent 別以三氟化硼 (Boron trifluoride diethyl etherate ，Ferak試藥級) cationic ring-opening polymerization at once when exposed to 及 DAI(diphenyliodonium hexafuorophosphate ,98+% Aldrich the UV light (λmax =254um). The polymer synthesized 試藥級)做為陽離子起始劑進行聚合反應。 DAI by UV curing had higher volume expanding ratio than that of the 為紫外光聚合時所使用的光起始劑(photoinitiator) ，經紫外光 corresponding polymer synthesized with BF 3． OEt2 照射後會進行下列反應 [6] ： as a catalyst. Fg. 1 Keywords: UV-curing , spiro-orthoester, expand monomer, photoinitiator, DAI ＋ 所形成的強酸 H PF則引發陽離子聚合反應。