NMR基础知识简介PPT.ppt

* * Detector si sigledirection.it can only detect the magnitization along detecting direction. * * * * * * * * * * * * * * * * * * * * In the example below the proton chemical shifts are referenced to the proton resonance frequency of TMS. (Set frequency scale to ppm (HZ/PPM); press calibrate;middle mouse button on TMS peak; type 0 ppm). * The presence of a nuclear spin will cause a small perturbation of its surrounding electron cloud. In the case of a chemical bond the electron clouds overlap, and as a result of this perturbation the neighboring spin feels a slightly different magnetic field