聚合反应原理Chapter6.ppt

Chapter 6 Synthesis and characterization of nonlinear polymers and block copolymers 6-1 introduction 6-2. synthesis 6-2-1 star block copolymers 1. The concept of star polymers 2. The approaches of synthesizing star block copolymers Anionic polymerization a. DVB method 4-arm star block copolymers (2). Cationic polymerization (b) Multi-functional initiator 3-arm amphiphilic star block copolymer c. Coupling method (3) Macromonomer technology 6-2-2 Graft copolymers 1. Basic concept of graft copolymers 2. Three general methods for the preparation of graft copolymers Grafting onto method Chemical modification of the main chain with the introduction of functional groups capable of reacting with performed polymers having active chain ends The polymer with functional group Block-graft copolymers have one linear block, whereas the other block is a graft copolymer b. Grafting from method From partially hydrolyzed polyvinyl acetate c Graft copolymer via macromonomers PSt-based macromonomers prepared anionically. Two methds are used to prepare macromonomers: functional initiation and electrophilic termination Functional group in the middle of the polymer chain II. Electrophilic termination III Copolymerization of macromonomers with conventional monomers The copolymerization can be radical, anionic, ring-opening polymerization, also can be condensation polymerization Free radical copolymerization (b) Macromonomers prepared anionically Although St is the most common monomer used for the preparation of macromonomers anionically, other monomers capable of anionic polymerization have been used The addition reaction of Si-H with vinyl group Coupling reaction of PMMA anion with p-bromomethyl styrene Copolymerization of macromonomers with conventional monomers The graft copolymers can be prepared by anionic, cationic, radical and condensation polymerizations of macromonomers with conventional monomers One example： polycondensation ( c). Macromonomer prepared by radic