阳离子性高分子定着剂及其疏水性修饰体在树脂及粘中兴大学森林系.pdfVIP

陽離子性高分子定著劑及其疏水性修飾體在樹脂及粘著物粒子去除上之應用 陽離子性高分子定著劑及其疏水性修飾體 在樹脂及粘著物粒子去除上之應用 蘇裕昌＊ Application of Cationic Polymeric Fixing Agent and its Hydrophobic Modification Products on Removal of Pitch and Sticky Particles Yu-Chang Su＊ Summary Hydrophobic substances such as wood pitch, white pitch and sticky substance are introduced into the papermaking system by the raw materials used. To reduce runnability problems caused by these substances ，treatment were made with addition of cationic fixing agents is a common met hod. Polyvinylamines has been developed successfully to meet this purpose. These new polymers have potential to enhance the reduction of hydrophobic particles. A series of polyvinyamines were used by a wide choice of molecul ar weights, cationic charge densities and hydrophobic functional groups. The bonding strength of fiber to fiber and particles to fibers were controlled ，and the aggregation of particles were surpressed resulting bet ter fixing performance and less deposition of these hydrophobic particles. The effectiveness of cationic polyvinylamine and polyet hyleneimine fixing agents and their modificati ons on lab studies and mill trials is demonstrated. Keywords ：Sticky substance, Pitch, White Pitch, Fixatives, Cationic Polymeric fixing agent,. Polyvinylamine(PVAm), Polyet hyleneimine (PEI), Deposition of pitch, White Pitch. 一、緒言 2 種物理化學的因子即其電荷、及粒徑被確認是特別重要。 木材樹脂、白樹脂以及粘著物質的表面一般所帯的陰離子電 最近製紙工業中最顯著的變化為清水使用量的減少與 荷遠比可溶性物質所帶的陰離子電荷低。因此，疎水性粒子 廢紙使用量的増加。因而導致製紙廠中造紙工程系統內有害 主要的禍害並非全是這些陰離子電荷所導致，而是疎水性物 物質的累積與沈著物的問題的發生 。一般的應用方法是是