环氧丙烷污水的微电解.docVIP

“微电解＋芬顿”法联合处理环氧丙烷污水的试验研究 许国平，杨军文,王湘，周付建，谭红 （岳阳长岭设备研究所有限公司，湖南岳阳414012） 摘要：利用“微电解＋芬顿”法联合对环氧丙烷生产污水进行预处理，考察了微电解反应时间、芬顿氧化pH、H2O2/Fe2+摩尔比、H2O2/CODCr质量比对污水中CODCr去除效果的影响。结果表明：在微电解反应2h、pH=3、气水比为10，及芬顿氧化反应2h、pH=3、H2O2/CODCr质量比为1.4%的最佳条件下，处理后出水CODCr降至2377mg/L，CODCr去除率为66.4%，达到排放至污水处理厂的水质要求。 关键词：微电解; 芬顿氧化; 环氧丙烷污水 Experimental Research of Epoxy Propane Wastewater by Microelectrolysis + Fenton Process Xu Guoping, Yang Junwen , Wang Xiang, Zhou Fujian , Tan Hong (Yueyang Changling Equipment Research Institute（Co.，Ltd）,Hunnan Yueyang 404102) Abstract: Epoxy propane wastewater was pre-treated by a method of microelectrolysis-fenton process. The effects of factors were researched, such as reaction time of the microelectrolysis process, fenton oxidation pH value, mole ratio of H2O2/Fe2 +, and quality ratio of H2O2/CODCr on the removing rate of CODCr from the epoxy propane wastewater. The results showed that, for the microelectrolysis process, the optimal condition was: the reaction time was 2 hours, the PH value was 3, the ratio of gas to water was 10:1; for the Fenton reaction, the optimal condition was: the reaction time was 2 hours, the pH value was 3, the quality ratio of H2O2/CODCr was 1.4. Under the above conditions, the total removal rate of CODCr reduced to 2377 mg/L, in other words, CODCr removal achieved 66.4%. So the pre-treated wastewater meet the requirements of water quality of discharging to sewage treatment plant . Keywords: Microelectrolysis; Fenton; Epoxy propane 1 前言 环氧丙烷生产过程中产生的污水属于高浓度有机废水，废水中含有大量的难生物降解物质，并对微生物有抑制作用[1,2]。中石化长岭分公司采用双氧水氧化法合成环氧丙烷，产生的污水含醇、腙、醚、酯蒽醌,高级氧化技术(AOPs)如微电解、臭氧氧化、湿式氧化、光催化氧化、芬顿氧化等被广泛应用于难降解有机物的预处理[5,6,7]。微电解法具有去除污染物效果好、运行简单、成本低的特点，还可提高污水的可生化性，利于后续处理。芬顿氧化法是水处理中应用较广的方法之一，具有更高的氧化效率、投资少、运行简单特点。本研究利用“微电解+芬顿”联合法对环氧丙烷污水进行预处理，微电解法可对原水中部分有机物进行有效降解，反应过程中产生的Fe2+和投加的H2O2作为Fenton试剂，进一步氧化废水中的难降解有机物，使出水符合进入污水处理厂的水质要求。本实验先对微电解法和芬顿氧化法的反应条件优化，再将两种工艺进行组合，最后得到最佳工艺条件。 2 实验部分 2.1 仪器及试剂 仪器：SYC-100标准CODCr消解仪，江苏省姜堰市HS-3C型H计上海雷GB 11914-89）。 3 结果与讨论 3.1 微电解法试验结果与分析 微电