钒酸铁类Fenton催化剂的制备及性能研究.PDFVIP

中国环境科学 2015,35(6) ：1734~1739 China Environmental Science 钒酸铁类 Fenton 催化剂的制备及性能研究 孙 浩 1,2,吴 娟 1*,马 东 1,孙玉颖 1,崔春月 1 (1.青岛农业大学资源与环境学院, 山东 青岛 266109 ；2.哈尔 滨工业大学(威海)海洋科学与技术学院, 山东 威海 264209) 摘要：在不同酸碱条件下,采用水热法制备了 FeVO4 催化剂,利用 XRD 、TEM 、FTIR 对产物表征,并将其作为非均相类 Fenton 催化剂氧化 降解有机染料罗丹明 B,研究了初始反应溶液 pH 值、类 Fenton 试剂中各组分的浓度、钒酸铁催化剂的制备条件等因素对类 Fenton 反应效 率的影响.结果表明,制备的钒酸铁 FeVO ﹒1.25H O,在优化条件下降解罗丹明 B 时 60min 内脱色率可达 97% 以上.与传统 Fenton 试剂相 4 2 比,类 Fenton 催化剂具有更广泛的 pH 适用范围,易于与水分离,应用前景广阔. 关键词：类 Fenton ；钒酸铁；水热法；非均相；罗丹明 B 中图分类号：X703.5 文献标识码：A 文章编号：1000-6923(2015)06-1734-06 Preparation of iron (III) vanadate Fenton-like catalyst and its catalytic performance. SUN Hao1,2, WU Juan1*, MA 1 1 1 Dong , SUN Yu-ying , CUI Chun-yue (1.Resources and Environment College, Qingdao Agricultural University, Qingdao 266109, China；2.School of Marine Science and Technology, Harbin Institute of Technology at Weihai, Weihai 264209, China). China Environmental Science, 2015,35(6)：1734~1739 Abstract ：Iron (III) vanadate catalysts were prepared by a hydrothermal method under different acid-base. The obtained samples were characterized by X-ray diffraction (XRD), transmission electron microscope (TEM) and Fourier Transform infrared spectroscopy (FTIR). The as-prepared samples were used as Fenton-like catalysts on the degradation of Rhodamine B (Rh B) which was used as a model pollutant. The effects of pH value, H2O2 concentration, iron (III) vanadate concentration and the type of iron (III) vanadate on the heterogeneous Fenton-like degradation of Rh B were investigated. The XRD patterns indicate that Iron (III) vanadate samples were FeVO ·1.25 H O. The decolorization rate of