官智第七章炔烃和二烯烃.pptVIP

6、聚合 炔烃与烯烃不同，它一般不聚合成高聚物，只发生二聚和三聚作用。如： 二、共轭二烯的结构 1、1，3-丁二烯键角120度，是一个平面型分子。 Relative Stabilities Structure of 1,3-Butadiene MO Energy Diagram Constructing Molecular Orbitals Pi molecular orbitals are the sideways overlap of p orbitals. p orbitals have 2 lobes. Plus (+) and minus (-) indicate the opposite phases of the wave function, not electrical charge. When lobes overlap constructively, (+ and +, or - and -) a bonding MO is formed. When + and - lobes overlap, waves cancel out and a node（节点） forms; antibonding MO. 1、请解释下列反应事实： 如： 共振极限式越接近等价，共振杂化体越稳定 节面数 对称性 E 3 C2 a-1.618