Environmental Chemistry - Home Robert Morris University：罗伯特莫里斯大学环境化学.pptVIP

* Industrial Hygiene Formaldehyde Analysis Copyright ? 2009 by DBS Contents Colorimetric Analysis Acetylacetone Method NIOSH 3500 Sampling Complaint area, non-complaint area and outside Vapor phase extraction followed by analysis MeasurementMethods Colorimetric Acetylacetone colorimetric method (Nash, 1953) NIOSH 3500 Pararosaniline Method HPLC GC See Schultz, M. and Salthammer, T (1999) for discussion of methods MeasurementAcetylacetone Colorimetric Method Acetylacetone colorimetric method (Nash, 1953) Hantzsch reagent (acetylacetone) 2M ammonium acetate, 0.05 M acetic acid, 0.02 M acetylacetone See Shimadzu paper No. A262 for method MeasurementAcetylacetone Colorimetric Method Stock HCHO solution = 37.7 % (m/m), ρ = 1.0108 g/mL Require HCHO std. (1000 ppm), how much of the 37.7 % solution should be taken to make a 100 mL solution of 1000 ppm HCHO? Dilutions of 1000 ppm to make a 1,2, and 5 standard? 1:100 to make a 10 ppm std., then 1:10, 2:10 and 1:2 MeasurementAcetylacetone Colorimetric Method Measure out 2x 25 mL of absorption liquid (DI water) into 2 impingers (sample and equipment blank) Pass air through one of the impingers at 1 L/min for 40 minutes Perform the following to: a 5 mL reagent blank, a 5 mL 1000 ppm Std., 5 mL of the air sample and the sample blank Add 5 mL acetlyacetone reagent and 5 mL DI water Heat for 30 mins at 40 °C Leave for color developemnt (30 mins) Dilute the standard to 1, 2, and 5 ppm Read standards and sample tubes at 412 nm, slit width 2.0 nm MeasurementAcetylacetone Colorimetric Method Shimadzu Paper No. A262 MeasurementAcetylacetone Colorimetric Method A Measurement NIOSH 3500: Chromotropic Acid Method UV-Vis NIOSH 3500 method uses chromotropic acid Detection limit: 0.5 μg per sample Measurement HPLC HPLC Health EffectsAcute Exposure Hess-Kosa, 2002 Summary Used in a wide variety of processes and products Carcinogenic, irritant poses safety hazard Max perm