New Features of the 2003 Release of the CMAQ Model - CMAS在2003版本的新功能- CMAS CMAQ模型.pptVIP

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2018-04-17 发布于江西
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New Features of the 2003 Release of the CMAQ Model - CMAS在2003版本的新功能- CMAS CMAQ模型.ppt

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New Features of the 2003 Release of the CMAQ Model - CMAS在2003版本的新功能- CMAS CMAQ模型.ppt

New Features of the 2003 Release of the CMAQ Model Jonathan Pleim1, Gerald Gipson2, Shawn Roselle1, and Jeffrey Young1 1 ASMD, ARL, NOAA, RTP, NC 2 AMD, NERL, USEPA, RTP, NC What’s new in CMAQ 2003 Updates to science Updates to Nitrate aerosol and Nitric acid Updates to Secondary Organic Aerosols Efficiency improvements Faster chemistry solver Modified model time stepping Other updates and corrections Air Quality Forecasting Nitrate Previous release (2002) shows large overprediction of Nitrate aerosol and Nitric acid Nitrate related changes Dry Deposition (winter) Added explicit resistance to snow and ice with dependence on temperature (melting) Modified cuticle resistance for NH3 as function of relative humidity Added wet ground similarly to wet canopy Revised model produces much greater Vd for NH3 thus reducing ammonium nitrate aerosol concentrations Heterogeneous and Gas-Phase Reactions Gas-phase nitric acid also greatly overpredicted Identified key pathway: N2O5 + H2O -- 2HNO3 Revised the heterogeneous reaction rate Turned off gas phase reaction Heterogeneous N2O5 Reaction 2002 release Reaction probability γ = 0.1 recommended by Dentener and Crutzen (JGR 1993) Makes a lot of HNO3 at night Recent studies show wide range of γ values Dependence on humidity, temperature, chemical composition - sulfate, nitrate, and organic content Updated version Reaction probability γ = 0.002 - 0.02 depending on NO3/(SO4+NO3) according to Riemer et al. (JGR 2003) based on lab measurements of Mentel et al (PCCP 1999) 2003 release vs 2002 release CMAQ02 vs CMAQ03 - Nitrate Secondary Organic Aerosols Corrections to Gas-Particle partitioning to allow reversibility Lowers SOA concentrations by 60-70% SOA precursor factors for SAPRC99 57% of ALK5 (longer chain alkanes) 93% of ARO1 (less reactive aromatics) Eliminated SOA from olefins SOA production in CB4 unchanged No production from alkanes or olefins 100% of aromatics Organic Carbon Aerosol CMAQ02 vs CMAQ03 - SOA Changes for impr