Convective Mass Transfer - NUS Singapore University College 对流传质-新加坡国立新加坡大学.pptVIP

* Lets consider a limiting case where the flow rate of the H2 rich feed gas to the reactor results in a bulk linear velocity of 100cm/s where trimethygallium is present in dilute concentration. We need to determine the local mass transfer coefficient for trimethylgallium in H2 gas at the center of the wafer using (a) boundary layer theory and (b) film theory. At sufficiently low flow rate within the reactor, the physical system represents convective mass transfer over a flat plate, where the hydrodynamic boundary layer develops before the concentration boundary layer. Trimethylgallium diluted in H2 gas serves as the source for mass transfer, and the reaction at the boundary surface is the sink for trimethylgallium gas. * * * This preceding analysis that we saw is valid for the limiting case where * * * * * * * Packed and Fluidized Beds For packed beds with single phase fluid and gas flow, Sherwood, Pigford and Wilke estimated 10 Re 2 500 where * Accounting for bed void fraction, ?, Wilson and Geankoplis correlation 0.0016 Re’’’ 55 and 165 Sc 70 600 and 0.35 ? 0.75 55 Re’’’ 1 500 and 165 Sc 10 690 Gupta and Thodos correlation 90 Re’’’ 4 000 * * * * * * The following examples illustrate the application of equilibrium relations for determining equilibrium compositions. * * * * * * * * * * * * * * * * * * * * * * Example 1 * * * * * * * Single Sphere Mass-transfer correlation If no forced convection, Sh = 2, * Transfer into liquid stream, the Brian-Hales equation for PeAB 10 000, For PeAB 10 000, Transfer into gas stream, the Fr?essling eq, 2 Re 800 and 0.6 Sc 2.7 * When no free or natural convection, With natural convection, the Steinberger and Treybal correlation, Where ScGr 108 ScGr 108 2 ? Re ? 30 000 and 0.6 ? Sc ? 3 200 * Spherical Bubble Swarm Eg. Bubbling of gas into liquid 2-part correlation from Calderbank and Moo-Young, db 2.5 mm, db ? 2.5 mm, * To calculate flux, must know gass holdup ratio, ?g, Propoti