都有为南京大学物理系.pdf

（都有为 南京大学物理系） NanoMaterials Nanometer-(nm)-The unit of length 1nm = 1 μm/103 = 10-9 m. 1nm=10Å Nano-materials: At least, one dimension of object on the nanometer size scale, 1-100nm. Nanoparticle (0D), Nanowire (1D), Nanofilm (2D), Nanocrystallite(3D) Composites : At least one composition is nanomaterial. Nanoarchitectonics Characteristic Physical Length-Lch Magnetic single domain 10nm －1 μ Superparamagnetic 1 －10nm Exchange correlation length 10-40nm Mean free path of electron 1 －10nm Spin diffusion length 10nm- 1 μ Wave length of light 400/700nm Small size effect; Quantum size effect; MQT (Macroscopic quantum tunneling) Surface effect Sv= S/V ∼ 1/d 磁有序材料: 铁磁, 亚铁磁,反铁磁 Br 磁性材料: 永磁,高 Hc,高K 软磁,低 Hc,低K Hc 磁记录,高Br 交叉耦合效应材料: 磁光,磁电,磁热,磁力 磁中性态 结构非灵敏性量: Ms, Tc, K, λ, 磁性材料(磁带） 结构灵敏性量: Hc, Br,μ, 的磁滞回线 ( Ⅰ).Magnetic Nano particles Applications Vortex KV=kT The characteristic physical length * Single domain : Rc ∝ (AK)1/2 M Fe Co Ni BaM Nb Fe B SmCo Sm Co N 2 14 5 2 17 2.3 Rc 8.0 11.4 21.2 450 125 400 180 (nm) *Superparamagnetism:KV=25k T B B M Fe O Ni Fe Co