路易斯碱低温碳化聚合物.pptxVIP

路易斯碱能提供电子云的分子或原子团称为路易斯碱。路易斯碱即电子给予体，是在酸碱电子理论定义下的碱，指可以提供电子对的分子或离子。任何在键结轨道中有孤对电子的分子均为路易斯碱。此处碱的定义和阿累尼乌斯对碱的定义不同，因此路易斯碱溶在水中不一定会产生氢氧根离子。氢键X-H…Y中的电子给予体Y是路易斯碱。 Poly(diiododiacetylene) (PIDA) Poly(diiododiacetylene) (PIDA) is a conjugated polymer containing an all-carbon backbone and only iodine atom substituents.PIDA is prepared by topochemical polymerization of monomer diiodobutadiyne within hostguest cocrystals. stable at room temperatureexplosive under external energy such as shock or pressure.Research coursethermal conditions, carbonization of PIDA fibers starts at 120 C, and complete carbonization can be achieved by pyrolysis at 900 C for 1 h.irradiated with a 532-nm Raman laser, the PIDA fibers transform irreversibly at room temperature to sp2-hybridized carbon. The generality of this iodine elimination further suggests that reaction of PIDA with Lewis bases dehalogenates the polymer, presenting a new method to prepare carbon nanomaterials at room temperature under very mild conditions.pyrrolidine, pyridine, and other amines, can react with PIDA to release iodine and thus carbonize the polymer at room temperature. 680 nm and a longer-wavelength absorption shoulder that is associated with the ggregation of the polymer chains 750 nmdecreases immediately after the base is added, indicating that the polymer starts to deaggregate.pyrrolidine causing a faster color transition than pyridine or triethylamine at the same concentration. no apparent peak above 450 nmfroma metallic luster to dark gray-black material maintains a fibrousmorphology after reaction with the Lewis basemixing bulk PIDA with neat pyrrolidine results in a dark, opaque suspension which is difficult to separate最初实验已证明:依赖于离子反应而非极性机制，在甲烷等非极性溶剂中反应很慢或几乎不反应，在四氢呋喃或吡咯烷极性溶剂中 反应，但是从极性溶剂中取出，反应不受到影响。更详细的机理还有待研究热重量分析图。降低很平缓。在原始聚合物150度开始降低，550时还有18%残留。处理过后聚合物550 C降低, 44%残留. PIDA 拉曼峰 971, 1407, 2074 cm1. 与吡咯烷反应后只有1360 1580 ，与碳纳米纤维 石墨碳类似表明不定形由于与吡咯烷反应或反应不完全，碳化不充分碳13核磁共振图谱表明这两种物质已有不同的结构和性能 初始的sp2 和 sp 在反应后都不在存在，被50~150的宽峰代替