al2o3掺杂cacetiwo系高温ntc热敏材料分析 word格式.docxVIP

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al2o3掺杂cacetiwo系高温ntc热敏材料分析 word格式.docx

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al2o3掺杂cacetiwo系高温ntc热敏材料分析 word格式

ABSTRACTWiththegrowingpopularityofthevehicleexhaustcatalyticconvertersinrecentyears, hightemperaturethermistorsarebecomingincreasinglyimportant.Negativetemperature coefficientthermistors(NTCR)arewidelyused,becausetheyaffordthebestsensitivityand accuracyatthelowestprice.NTCmaterialsthathavebeenputintousearemostlyspinel structureformedbysolidsolutionsoftransitionmetaloxides,suchasMn3O4,Co3O4and NiO,butthistypeofNTCthermistorsisusuallyapplicablefortemperaturemeasurement below300°C.ScheelitestructureNTCmaterialsarefoundtobeexpectedforhigh temperaturethermometryrecently.Therefore,thispaperstudiedtheNTCcharacteristicsin Ca-Ce-Ti-W-Osystemat high temperature carefully, and got stable NTCceramicmaterials.CaWO4-CeTi2O6ceramicswerepreparedbyhightemperaturesolidstatemethod,the effectoftheCeTi2O6 contentonthephasecomposition,microstructure,electricalproperties andhightemperaturestabilitywassystemicallyinvestigated.ThesamplesshowedgoodNTCcharacteristicsover25－800°Caftersinteringat1300°Candthemaincrystallinephase wasscheelite CaWO4phase.WithanincreaseinCeTi2O6contenttheaveragegrain sizeincreased,howevertheresistivityandagingcoefficientdecreased.Theexistenceof electronhoppingbetweenCe3+/Ce4+,whichcausedthematerialstoexhibitsemiconducting behavior, has been confirmed by XPS analysis.TheeffectofthehighresistancephaseAl2O3onthephasecomposition,microstructure, electrical properties and high temperature stability for CaCe0.5TiWO10 ceramics wassystemicallystudiedforthefirsttime.Allthesamplessinteredover1300－1360°ChaveNTCcharacteristics.Atthesamesinteringtemperature,theresistivityincreasedwithan increaseinAl2O3 content,whereastheagingcoefficientdecreased.TheagingcoefficientofthesesampleswhichhavesameAl2O3 contentdecreasedtominimalvalue1.48－5.10%,andthenbegantoincreasewithariseinsinteringtemperature.Themaincrystallinephaseof thesesampleswasscheelite CaWO4phaseandaverysmallamountofcubicCa3Al2O6phaseIIwhensinteringat1340°C.WithanincreaseinAl2O3content,smallgrainsincreased graduallyandatta