al2o3eppubf层压板的制备及性能分析 word格式.docxVIP

Al2O3-EP-PU/BF层压板的制备及性能研究摘要环氧树脂（EP）因其良好的胶黏特性和优良的介电性能大量用于绝缘材料；玄武岩纤维（BF）具有优异的化学稳定性、耐高温性、绝缘性。本文以环氧树脂为基体，纳米氧化铝、聚氨酯（PU）为增韧改性剂，玄武岩纤维为增强体制备了Al2O3-EP-PU/BF层压板。采用红外光谱（FT-IR）、扫描电镜（SEM）、X 射线衍射（XRD）表征Al2O3/EP-PU基体，研究了基体的化学结构及微观形貌；SEM表征硅烷偶联剂（KH550、KH560、KH570）改性BF及复合材料微观形貌，分析BF 与Al2O3/EP-PU基体之间界面对Al2O3-EP-PU/BF复合材料力学性能及介电性能影响。控制PU、EP、Al2O3配比，测试Al2O3/EP-PU的剪切强度、剥离强度、拉伸强度、冲击强度、及相关介电性能和耐热性。结果表明：当PU添加量为15wt%，Al2O3-EP-PU的冲击强度、拉伸强度和剪切强度分别提高约65.65%，35.33%和22.37%，纳米Al2O3掺杂量为2wt%时，Al2O3-EP-PU综合性能提高。以Al2O3/EP-PU和改性的BF制备了Al2O3-EP-PU/BF层压材料。测试材料冲击强度、弯曲强度表明硅烷偶联剂表面处理BF可提高Al2O3-EP- PU/BF界面粘结性能，弯曲强度顺序是：KH550-CMKH560-CMKH570- CMuntreated-CM，冲击强度也是KH550-CMKH560-CMKH570- CMuntreated-CM；变频介电损耗测试及理论计算界面层介电损耗，分析偶联剂改性BF对形成纤维与树脂界面层介电损耗的影响，研究表明Al2O3- EP-PU基体与KH560-BF形成界面层的介电性能比其与KH550-BF，KH570- BF及未处理BF形成的界面层介电性能优异。结合SEM表征及测试材料介电损耗、击穿强度拉伸强度，系统研究了挥发物含量、树脂含量对材料力学、电学性能的影响。挥发物含量由4wt%增加到6wt%，tanδ增加近三倍，材料的介电强度也随着挥发物增加而降低；树脂含量25wt%~35wt%范围内，随树脂增加拉伸强度从345MPa增加到531MPa，增加约53.9%，变化趋势显著；树脂高于35wt%后，拉伸强度下降。关键词环氧树脂；聚氨酯；nano-Al2O3；BF；介电性能；PreparationandPropertiesofAl2O3-EP-PU/BFAbstractEpoxyresiniswidelyusedforinsulationmaterialbecauseofitsgood adhesionpropertiesanddielectricproperties,Basaltfiberhasexcellentchemical stability,hightemperatureresistanceandinsulation.Al2O3-EP-PU/BFcomposite materialswerepreparedbyepoxyasmatrix,methyltetrahydrophthalicanhydride asthecuringagent,polyurethaneandAl2O3astougheningagent,themodified basaltfiberasreinforcement.Inthispaper,Al2O3/EP-PUmatrixwereCharacterizedbyFouriertransform infraredspectrometer(FT-IR),Scanningelectronmicroscope(SEM)andXRD, themechanismofepoxyresintoughenedbyPU,curingmechanismofresinand theorganicmodificationofnanoparticleswereresearched. BasaltFibres(BF) modifiedbythreekindofsilanecouplingagent(KH550,KH560,KH570)were observedbySEM.ThemicrostructureofAl2O3-EP-PU/BFwascharacterizedby SEMforresearchingtheeffectofthebasaltfibersurfacetreatmenton mechanical properties and electrical properties of composite material. ThepercentagecompositionofPUandnano-parti