固废气废微生物过程教程.pptVIP

* * 主导微生物：Thermophilic Microorganisms 温度: 45-60 oC 优点: Higher degradation rate；More economical treatment processes 缺点: Fast decomposition of degradable support media； Reduction of the solubility of pollutants 应用: Deshusses et al. (1997): ethyl acetate, 45-50 oC van Groenestijn. (1995): ethanol , 50-70 oC 典型 Biofilter 4—高温Biofilters * * 主导微生物: Nitrobacter: Nitric oxide ? Nitrite ? Nitrate Denitrifying bacteria: NO ? N2 代谢类型：Aerobic / Anaerobic Processes 应用: Apel et al. (1995): Anaerobic removal of nitrogen oxides from combustion gases using denitrifying bacteria (NO ? N2 in thick biofilm ) Biosaint (1999): Removal of ammonia using Nitrobacter:95-98% removal at 50-1000 ppmv 典型 Biofilter 5—高温Biofilters * * Growth substrate (CH4, toluene, phenol, etc.) M.O. 三氯乙烯(TCE) CO2, H2O Biomass Microorganism: no energy or other benefits from degrading cosubstrate? fortuitously degrade unrelated compounds (similar shape to the active site of the enzyme) 典型 Biofilter 6—共代谢Biofilters * * Parameter Biofilter layer height Biofilter area Waste air flow Biofilter surface loading Bed void volume Mean effective gas residence time pressure drop per meter of bed height Inlet pollutant and/or odor concentration Operating temperature Inlet air relative humidity Water content of the support material pH of the support material Typical removal efficiencies Typical value 1-1.5 m 1-3000m2 50-300,000m3h-1 5-500m3m-2 h-1 50% 15-60 s 0.2-1.0 cm water gauge (max. 10cm) 0.01-5g m-3, 500-50,000OUm-3 15-30 C 98% 60% by mass pH 6-8 60-100% 典型 Biofilter 运行条件 * * 生物吸收法的工艺一般由废气吸收段和悬浮液再生段两部分组成，相应的装置为吸收设备和再生反应器 ,具体工艺流程如右图所示 (2)生物吸收法 * * 曝气式系统由曝气池和池内的曝气管构成，用含有有机化合物的空气作为曝气空气送入曝气池，通过池中的活性污泥使有机物氧化分解，故可同时处理废水与废气。 生物吸收法适于处理气量小、浓度大的有机废气，特别适于处理易溶、相对易被氧化的化合物，不适于处理有机硫化物、难氧化的化合物。 生物吸收法的适用性 * * 生物滴滤法工艺集生物吸收和生物氧化于一体。气体从生物滴滤器的底部进入填料层，然后与回流水接触，便于最大限度地吸收进入液