搀杂氧化铈-碳酸盐电解质中离子传导及燃料电池性能-工业催化专业论文 word格式.docx

ABSTRACTLoweringtheoperatingtemperatureisakeyrequirementforthecommercializationofthesolidoxidefuelcell.Apromisingelectrolytematerial,oxide- inorganicsaltcomposite,whichhasahighionicconductivityinthetemperaturerangeof500-650oC,hasbeeninvestigatedextensivelyinrecentyears.Thisworkfocuses ontheconductingmechanismsofO2-andH+inthesamariumdopedceria(SDC)- carbonatecompositeelectrolyteswithdifferentcomponents,andtheeffectfactorsofthefuelcellperformance.Inchapter2,theSDCpowdersaresynthesizedbytheoxalatecoprecipitationmethodandthecarbonatecoprecipitationmethodrespectively,andmixedwithNa2CO3or(Li0.52Na0.48)2CO3toformthecompositeelectrolytes.Theeffectsof preparingmethod,compositionandmixingprocessonthestructureandpropertyof thecompositeelectrolytesareexaminedbyXRD,SEMandTG-DTA.TheSDC retainsitsintrinsicalcharactersinthecomposite,andpossessesahighchemicalstabilitywiththecarbonate.ThedistributionofthetwophasesandtheAC conductivityofthecompositearehighlyinfluencedbythecarbonatecontentandthemixingmethodinthepreparationprocess.In chapter 3, the conductions of H+ and O2- in the SDC-(Li0.52Na0.48)2CO3compositeelectrolytemadebytheoxalatecoprecipitationrouteareinvestigatedby theH2 andO2 electrochemicalpumpingmethods,whicheliminatetheerrorscausedbythegasleakagethroughcompositeelectrolytemembraneseffectively.Thecompositematerialsshowefficientconductivitiesofbothofthetwoionsat650oC.BothoftheconductivitiesofH+andO2-improvedwiththeincreaseofthecarbonatecontent,implyingthemoltencarbonatephaseprovidedapathfortheconductionof bothofthetwoions.Theeffectoftheoperatingtemperatureontheconductivitiesofthetwoionsisalsostudied.Inchapter4,thedirect-currentfour-probemethodisemployedtoinvestigatetheeffectsofspeciesandcontentofthecarbonateandthedistributionofthetwophases inthecompositeelectrolyteontheconducitvitiesofO2- andH+.Meanwhile,theconductivities of O2- and H+ inthe SDC-(Li0.52Na0.48)2CO3 made by the oxalatecoprecipitationmethodarecalculatedusingtheeffectivemediumpercolationtheory, and