掺杂钡铁氧体-二氧化钛碳纳米管聚噻吩基复合材料制备及性能研究-应用化学专业论文 word格式.docx

噻吩复合物的微波吸收能力最强。（4）DTA-TGA分析表明BaFe11.92La0.04Nd0.04O19铁氧体-二氧化钛/碳纳米管/聚3-甲基噻吩复合物分解过程分为三个阶段，前两个阶段为掺杂铁氧体-二氧化钛复合物分解过程，第三个阶段为聚3-甲基噻吩的分解过程。SEM和TEM表明铁氧体-二氧化钛复合物、碳纳米管被包覆在聚3-甲基噻吩中。通过电磁参数性能表征发现，聚3-甲基噻吩和纳米碳管的引入，急剧提高掺杂铁氧体-二氧化钛复合物的电导率，极大改善铁氧体-二氧化钛复合物的微波吸收性能，拓宽了吸收频带，吸波效果明显大于聚噻吩基复合材料。当碳纳米管含量为7.7 wt%时，掺杂铁氧体与二氧化钛比值为3:5，掺杂铁氧体-二氧化钛/纳米碳管/聚3-甲基噻吩复合物的微波吸收能力最强。关键词:掺杂钡铁氧体；二氧化钛；碳纳米管；导电聚合物；电磁性能AbstractMoreandmorewave-absorbingmaterialshavebeendevelopedatpresent,butsinglematerialcannotmeettherequirementsofstrongabsorptionandwideabsorptionfrequencyband,duetoitsweakabsorption,narrowabsorptionfrequencyband,andheavydensityandsoon.Compositematerialswhichincorporatedifferentfunctionsandcharacteristicsofindividualmaterialmaydevelopnewfunctionalmaterialsandsolvethoseproblems.Inrecentyears,magnetic-conductivecompositeswithexcellentperformancehaveattractedwideattentionbecauseofadjustableelectromagneticperformance,lightinweight,easypreparationandsoon.Dopedferrite/titaniumdioxidecompositeswerepreparedthroughthesol-gelself-propagatingcombustionmethod.Aseriesofnewelectromagneticlosstypepolythiophene-basedwave-absorbinghybridnanocompositewereobtainedbythein-situchemicaloxidationpolymerizationmethod.Thebetterwave-absorbingperformancewillbeobtainedbythesynergisticeffectofrareearthelementdopedferrite,titaniumdioxide,carbonnanotubesandpolythiophenederivatives.Therelationships between the material composition-preparation technology-structure-propertieshavebeendiscussed,basedontheXRD,FTIR,DTA-TGA,SEM,TEM, VSMandconductivitystructureandpropertytestsandtheelectromagneticparametercharacterizationofcomplexpermittivity(εr)andcomplexpermittivity(μr). Thecompositewave-absorbingmechanism hasbeeninvestigatedfromthemacroscopicaspectandthemicroscopicaspect.Themainresearchworkandconclusionsareasfollows:XRDandSEMhaveindicatedthattheoptimumcalcinationtemperatureof BaFe11.92La(0.08-x)NdxO19ferriteis1000℃.Rod-likerareearthdopedferriteparticlespossessgoodmagnetismwithadiameterin100nm.Rareearthelementcanadjustthemagneticparameters.