大环草酰胺配合物配体及配位聚合物的合成、结构和性质-无机化学专业论文 word格式.docx

obtained unexpectedly. The result of the attempt is of guiding significance for future design and synthesis of new metalloligands.Keywords: Coordination polymer, Metalloligand, Macrocyclic oxamide, Zigzag chain, Helical chain目录第一章绪论.............................................................................................................................. 11.1 配位聚合物的概念........................................................................................................... 11.2 配位聚合物的组成和空间结构....................................................................................... 21.2.1 中心金属离子........................................................................................................ 31.2.2 桥连有机配体和金属配合物配体........................................................................ 41.2.3 阴离子和溶剂分子................................................................................................ 91.2.4 一维配位聚合物.................................................................................................. 101.2.5 二维配位聚合物.................................................................................................. 181.2.6 三维配位聚合物.................................................................................................. 211.3 影响配位聚合物结构的主要因素................................................................................. 241.3.1 配体对配位聚合物结构的影响.......................................................................... 241.3.2 溶剂和浓度效应.................................................................................................. 261.3.3中心金属离子的变化影响.................................................................................. 271.3.4 反应的 pH 值效应 281.3.5 其他反应条件对配位聚合物结构的影响..........................................................291.4 配位聚合物的合成方法................................................................................................. 291.4.1 溶液结晶法....................................................................................