醇类电氧化过程中非线性振荡行为研究-应用化学专业论文 word格式.docx

醇类电氧化过程中非线性振荡行为研究英文摘要Study of nonlinear oscillatory behavior during alcohols’ electro-oxidationAbstractThe electro-oxidation reaction mechanism study of small organic molecules is very important for both fundamental science and applied science. Practical application in fundamental investigation,one of the significances lies in enriching nonlinear dynamic theory by analyzing the electrochemical oscillation mechanism during the small organic molecule electro-oxidation reaction, which in applied sciences, our study provides theoretical guidance on developing a high-performance fuel cell and benefits for searching high efficient electrocatalysts.The main work of this paper can be summaried as follows: The electro-oxidation reaction mechanism of eight alcohol (methanol, ethanol, glycol, n-propanol, 1,2-propanediol, propanetriol, n-butyl alcohol, 1,4-butanediol) were studied using electrochemical methods such as Cyclic Voltammetry (CV), Electrochemical Impedance Spectroscopy (EIS) , Linear Sweep Voltammetry (LSV) and Galvanostatic /Potentiostatic Measurement etc. We try to find the origin of every oxidation peak and reduction peak displaying in cyclic voltammograms and to find the parameter space in which the alcohol solution system can display nonlinear behavior of every alcohol solution system. Besides, we analyzed the relationship between negative faradic resistance and potential applied outer, aiming to look into the causes of negative faradic resistance. Meanwhile, the influences of alcohol solution concentration and applied current and/or potential value on electrochemical oscillation were analyzed and the parameter space exhibited in electrochemical oscillation was experimentally invesigatigated. Finally, we discuss intensively the electrochemical behavior of some alcoholic solution system by referring related reports.英文摘要醇类电氧化过程中非线性振荡行为研究The dependence of the electrochemical impedance spectroscopy (EIS) on the applied potential as follows: when the electrode poten