利用粉煤灰制备分子筛及其处理焦化废水的研究-化学工艺专业论文 word格式.docxVIP

Study on zeolite making use of fly ash and processing the coking wastewater AbstractCoking process of wastewater and coal combustion process of fly ash belong to recent large the pollutants and waste, how can the governance of high pollution of coking wastewater low consumption and rapidly, become the urgent to solve the problem. And fly ash as the product of coal burning, annual emissions to hundreds of millions of tons, due to the lack of effective management of fly ash, not only to environmental pollution, and serious harm to human health.In this paper, propose applied fly ash with high activity for the basic raw material, fluidized bed by hydrothermal synthesis method, the direct enclosed with lye, molecular sieve successfully synthesis reactions. At the same time, the experiment also makes zeolites to be acidification modification, in order to improve the removal of molecular organic pollutants, and study on two fitted isothermal adsorption curve, explore the factors affecting the adsorption. Experiments show that use synthetic zeolites processing coking wastewater, adsorption 20min, absorption basic saturation, rapid rate of organic adsorption, it has the good effect , the removal rate could reach 77.5%, The removal of organic molecular size dosage of zeolite synthesis increases, when the concentration of 400mg/L 50mL 3g zeolites (add water, COD fell after 80 percent, with the increased amount of additive, removal increased slowly. By the adsorption isotherm, this method the preparation of the largest adsorption capacity can reach 7.89 mg/g.By using zeolite adsorb organic matter, after molecular sieve adsorption the experiments focused on saturated organic adsorption of molecular sieve regeneration research. Research shows that the experiment uses the method of chemical synthesis, molecular sieve, regeneration rate up to 86.44%. The zeolite can be regenerated and repeated use, with asecond regeneration rate of drop rate is compared to regenerate.