氢化态mg-mn复合物水反应行为研究-材料学专业论文 word格式.docxVIP

温度反应时产物稳定的分散性，改性效果显著。氢化态Mg-Mn复合物与NaCl溶液反应产物沿颗粒法向方向呈交叉片状长大。Cl-离子的存在使团聚效应明显，分散性较差。因此，“反应改性”这一概念更适合于氢化物与二次去离子水反应体系。针对氢化物反应量不同的探索性试验研究结果表明：参与反应的氢化物质量越大，反应温度升高，其非极性的（001）晶面显露量急剧增多，进而使水反应产物--Mg(OH)2分散性越好，通过反应到达改性的效果越明显，有望发展成为一种短流程制备改性氢氧化镁的新方法。关键词：氢化态Mg–Mn复合物；水反应产物；特性吸附；反应改性；Mg(OH)2AbstractEfficienthydrogensourceandreal-timehydrogenproductionandsupplyarethecoretechnologiesforthehydrogenapplicationinthefuture.MgH2reactswithwatertoobtainH2、Mg(OH)2andreleaseheat.Itisexpectedtobeanewportablehydrogensourcetechnologywithhighlyefficient.However,thebottleneckproblemthatretardsitsapplicationisthecharacteristicthattheproduct--Mg(OH)2iseasilyattachedtothesurfaceofunreactedMgH2tostopthereaction.Sothefocusofthispaperistheformulationofmaterialsandthestudyontheprinciplesofreactionwithwater.Inthispaper,Mg-MncompositepowdersandpureMgpowderswerepreparedbyballmillinginhydrogen,andtheirhydrogenatedpowderswerecharacterizedbyX-raydiffraction(XRD)andthescanningelectronmicroscope(SEM).Thebasiclawofthehydrolysiskineticsofthesehydrogenatedcompositesmeasuredbyhome-madedevicewasanalyzed.Themorphologyofreactionproducts--Mg(OH)2wasalsocharacterizedandthebasiclawofmorphologyprogressionwasqualitativelyanalyzed.Theresultsshowedthathydrogenatedcompositepowderscouldbepreparedbyballmillinginhydrogen.Boththehydrogenationprocessandthefinalgrainsizesofthecompositepowderswereinfluencedbytheratioofballtopowderandtheequal-fineparticlesapproximatedtotheequiaxedwasthefinalmorphology.Duetotheincreasedactivityofmagnesiumandthemixingofasmallamountofoxygenintohydrogen,hydrogenatedMg-MgOcompositepowderswerepreparedultimately.TheparticlesizesofhydrogenatedMg-MncompositesandhydrogenatedMg-MgOcompositesvariedinrangof1~7μmand1~4μmrespectively.ThehydrolysiskineticsofhydrogenatedMg-Mncompositesismarkedinfluencedbythereactiontemperatureandwaterquality,andthekineticsisoptimizedandhydrolysisrateandreactionrateareimprovedasthetemperaturerisesinthetemperaturerangeofthisexperimentisthebasicrule.Whenreactwithsecondarydeionizedwateran