悬浮法生产聚苯乙烯 -刘志文.doc

高分子合成工艺设计说明书 题 目 院 、 部： 材料与化学工程学院 学生姓名： 刘志文 指导教师： 罗建新 职称 讲师 专 业： 高分子材料与工程学院 班 级： 1001班 完成时间： 2013年6月2日 摘 要 可发性聚苯乙烯（Expandable PolyStyreneEPS）通称聚苯乙烯和苯乙烯系共聚物，是一种树脂与物理性发泡剂和其它添加剂的混合物。最常见的可发性聚苯乙烯是含有作为发泡剂的戊烷的透明PS粒料。 Abstract Expandable Polystyrene (Expandable PolyStyrene, referred to as EPS) commonly known as the Department of polystyrene and styrene copolymer is a kind of mixture with resin the physical blowing agent and other additives mixture. The most common is to be made of polystyrene with n-pentane as a blowing agent aggregates of transparent PS. The design is about of polystyrene polymerization process section that the annual production capacity is32000 tons, The reaction mechanism is free radical polymerization, suspension polymerization process used styrene as monomer, water suspension medium done using one-step production of low-temperature suspension polymerization process. This method is adding styrene monomer, initiator, dispersing agent, water, blowing agent and other auxiliaries to reactor, the polymer containing a foaming agent, after the resin particles by washing, centrifugal separation and drying, the system may be made of polystyrene beads products; mainly contrapose the polymerization reactor carried out for material balance, heat balance, in this based on the analysis process to select out of the process equipment and calculate and draw the flow chart with control points. And the preparation of the design specifications and calculations of the book. Key Words：xpandable polyStyrene ；suspension technique ；craft calculation； technological design 目 录 第一章 绪论 1.1聚苯乙烯简介 6 1.2聚苯乙烯的基本物性 8 1.3国内外的现状及发展前景 第二章 工艺流程和方案的说明及论证 2.2发泡聚苯乙烯技术工艺比较 2.2.1塔式本体聚合技术[3] 9 2.2.2 添加少量溶剂的单釜连续本体聚合技术 10 2.3 苯乙烯的悬浮聚合[4] 11 2.4苯乙烯种子法悬