激光诱导击穿光谱技术用于土壤成分检测研究汇总.pdf

摘 要 66% 。实验证明了较高的激光脉冲重复频率能够进一步改善等离子体光谱质量，这对于 降低光谱分析检出限，提高检测灵敏度尤为重要。 4. 利用激光诱导等离子体光谱技术进行土壤中重金属元素的定量分析 以国家标准土壤样品（GBW07411 ）作为分析试样，在优化的实验条件下，测量了 土壤等离子体发射光谱，并采用标准加入法对样品中有毒重金属元素铬进行了定量分 析。实验结果表明，当采用内标元素谱线来消除实验条件波动带来的不利影响时，获得 的定量分析结果令人满意，证明了激光诱导等离子体光谱技术用于土壤元素成分检测的 可行性。 关键词 激光诱导等离子体 散焦激光束 样品添加剂 激光脉冲重复频率 光谱质量 土壤 II Abstract Abstract In this paper, the spectral characteristics of laser-induced soil plasma were studied.The laser spectrum analytical system is composed of a SQ-II Nd ：YAG laser(0～700 mJ),a plane grating spectrograph and a spectral collection and data processing system. National standard soil samples were used as ablating target.The main subjects are as the following: 1. The influence of laser pulse energy and defocusing of laser beam on plasma radiation. The influence of laser output energy （100-500 mJ）and on the radiation intensity was studied. The results show that both the line intensity and signal-to-background ratio of plasma emission spectrum can be enhanced under the optimized condition that the laser energy was 200 mJ . The quality of spectrum was further improved after the laser beam used to excite the sample was defocused properly. When the defocusing position was +6 mm,the spectral lines intensity of element Mg、Al 、K and Fe increased about 46% 、63%、59% and 45% than that without defocusing respectively. The spectral signal-to-background ratio increased about 11%、31%、35% and 38% respectively. Thus proved that proper laser energy and proper defocusing of laser beam can strengthen the radiation of laser-induced soil plasma distinctly. 2. Enhancement effect of NaCl additive on laser-induced soil plasma radiation The enhanceme