GCms同时测定油脂性的食品及食品添加剂中16种邻苯二甲酸酯类.doc

GC-MS同时测定油脂食品中16种邻苯二甲酸酯类迁移物赵云霞蒋俊(*周成林镇江出入境检验检疫局，国家食品添加剂及调味品检测重点实验室，镇江 212008摘要：采用气相色谱电子轰击离子源质谱(GC-EI-MS)技术分析油脂性食品及油脂性添加剂中16种邻苯二甲酸酯 ( PAEs)环境激素的迁移量。GC-EI- MS选择离子检测(SIM)进行定性和定量分析，优化出了油脂性基质的系统前处理方法。当样品的加标浓度水平分别为 0.25和 0.50 mg/时，加标回收率为 58.9 -111.1%，相对标准偏差为1.0- 4.6%。16种PAEs在0.1-2.0 mg/L浓度范围内16种PAEs都呈现良好的线性关系，r为 0.9960- 0.9995检测限()均为70 μg/kg。方法已用于8批油脂性的食品和7批油脂性食品添加剂中16种痕量PAEs迁移物的分析。本研究对制定食品及添加剂中PAEs成分的检测标准和限量要求，具有重要意义。 关键词: GC-EI-MS，油脂类食品及添加剂，邻苯二甲酸酯，迁移物 imultaneouly determination of 16 Phthalates migrants in oleaginous foods and food additives by GC-MS ZHAO Yunxia, JIANG Jun*, YU Yang, ZHOU Hong-bin, LI Ping, WANG Zu-xiang, ZHOU Chen-lin (State Key Laboratory of Food Additive and Condiment Testing,Zhenjiang 212008,China) Abstract: Determination of sixteen kinds of Phthalates(PAEs) migrants in oleaginous foods and food additives were established simultaneously by gas chromatography mass spectrometry with EI power source.The qualitative and quantitative analysis were used with SIM mode. Pre-treatment methods of oleaginous matrixes were optimized systematically. The recovery level was 0.25 and 0.5mg/kg, the average recovery rate was in the range of 58.9 -111.1%, the RSD of precision was 1.0- 4.6%, respectively. The detection limits of method were 0.07- 0.70 μg/kg. The linear range was 0.1-2.0 mg/L, with determination coefficients in the range of 0.9960- 0.9995. The methods in this paper were used for quantitative analysis of Phthalates(PAEs) in eight batches of oleaginous foods and seven batches of oleaginous additives. This study is important of testing standards ,limits and quality control of Phthalates(PAEs) in foods and food additives. Keywords: GC-EI-MS, oleaginous foods and oleaginous additives, Phthalates, migrants 邻苯二甲酸的酯类化合物(PAEs)是塑料生过程中一种改性添加剂，用于提高塑料的强度和增强可塑性。PAEs与塑料分子之间由范德华力或氢键联接，仍然保留其相对独立的化学性质。随着塑料包装材料与食品长时间地接触，PAEs类成分，可从塑料中食品中[13]。有研究表明，PAEs能干扰机体正常的激素分泌水平，导致激素水平紊乱[4-6]。 欧盟2009/48/EC指令、台湾标准检验CNS 4797法案、加州AB 1108法案、美国CPISA消费者改进法案中均对食品、玩具等多种产品中的DEHP、DBP、BBP、DINP、DI