复旦大学 无机化学IC23.pptVIP

Chapter 5 d-block elements(II) organometallic compounds new type of reactions unusual structures applications in organic synthesis and industrial catalysis structures bonding reactions 5.1 The features of organotransition metal compounds definition: an organometallic compound contains one or more metal-carbon bonds. Main-group organometallic compounds Organotransition metal compounds element-carbon element-hydrogen M—C E—C Organic ligands and Nomenclature Classification I A ,II A (heavier metals) M -L ionic Li Be B electron-deficient comp. Mg Al Molecular electron-poor polymeric Ⅳ A electron-precise comp. ⅤA,ⅥA ⅦA molecular electron-rich Organometallic compounds of s- and p- block elements Organometallic compounds of d-block M-C both sigma (σ) bonds and pi (π) carbon σdonor carbon σdonor/πacceptor carbon πdonor/π acceptor M C O CH2 π-acid ligands M π- ligands CH2 Common types of ligand σ-bonded alkyl, aryl and related ligands carbonyl ligands hydride ligands phosphine and related ligands dinitrogen dihydrogen π-bonded organic ligands Alkenes R2C=CR2 η-Nomenclature for ligands Greek prefix η (eta) describes the number (n) of atoms in a ligand which directly interact with the metal centre,the hapticity of the ligand Example : Cyclopentadienyl ligand [C5H5] or Cp. is versatile in its modes of bonding, 5.2 σ-alkyls and aryls of  transition metals IVB VB VIB VIIB Me4Ti Me5M Me6W RM(CO)5 Me3TiCl (Nb,Ta) CpM(CO)3R Mn,Tc.Re Me4Ti· en (C5H5)2VR Cr,Mo,W V(C6H5)6 VIII IB CpM(CO)2R