东乌旗煤及不同化学组分热解动力学及其挥发分析出规律的分析-矿产普查与勘探专业论文.pdf.docx

太E历FEVOLUTION KINETICS AND MECHANISMSOF VOLATILE FROM DONGW UQI LIGNITE ANDDIFFERENT CHEMICAL COl\tIPONENTSABSTRACTThe majority of scholars ha s paid more attenti on to lignite ，beacause of the reserves and widely u se of it. Based 00 analysi s of FTIR aod TG-MS ，the kinetics of pyro)ysi s and the emissioo ofpyrolysis gases were studied 00 Wuniteligoite ，the humic acid ，the residuals after humic acid was removed ，the asphalt aod the residuals extracted by pyridine. Maio cooclusioos are drawn as follows: l.The structure cbaracteri stic: the fa is reduced with the increase ofHJC and increase with the increase of O/ C; there are environmen t of polarity exist in coal and five replace modes ofbenzene; at the influence ofthe acid and alkali ，the aromatic vibretion peak and aliphatic stretching vibrat ioo become weaker; after the extracted by pyridine ，the peak attributable to the aromatic struc阳re becomeweaker.The characteristics of coal during pyrolysis: as lignite is a low raok coa]，the temperatures of coal during the initial pyro lysis is low; beca use of the impact of the pyridine，tbe asphalt and asphalt residues are more prone to thermal decomposit ion，1055 bigger weight and response quickily; as the glial body is oot大l京到工大学硕 士研究生学位论文generated during coal pyrolysis ，the higher reactivity of char，the activation energy of the most violent phase of pyrolysis is higher than the final stage.The interaction between the pyrolysis gases: Jignite cont ains more waterthao other coaJ; the aliphatic chain of the oxygen-containing functional group generate methane，water and carbon dioxide during pyroJysis; As the environmental impact of acid-base ，the type of the keys which generate methane reduce ，the number of keys increase; because of pyridine ，the type and numberofthe keys which generate hydrogen and methane increase.The characteristics of the gas escape from pyrolysi s: the water during pyroJysis mainly from the dehydration of carboxyl and phenolic hydroxyJdehydr