材料科学基础（双语）II.ppt

第十章 烧结过程——10.1烧结概述 1. Definition 压制成型后的粉状物料在低于熔点的高温作用下、通过坯体间颗粒相互粘结和物质传递，气孔排除，体积收缩，强度提高、逐渐变成具有一定的几何形状的块体材料。 Transform compact powders to bulk solids at high temperature below melting point. 第十章 烧结过程——10.1烧结概述 2 Classification Solid State Sintering(固相烧结)： pure solid without any liquid phases at high temperature during sintering Liquid State Sintering(液相烧结)： solid phase and liquid phase at high temperature during sintering 第十章 烧结过程——10.1烧结概述 3 Relation between sintering and melting temp. Relation between Ts and Tm of pure materials： Metal powders: Ts≈（0.3~0.4）Tm Inorganic salts: Ts≈0.57Tm Silicates: Ts≈（0.8~0.9）Tm Ts ? the temperature at which mass points start to migrate. 第十章 烧结过程——10.2烧结过程及机理 10.2 Sintering Process and Mechanisms Sintering process Drive force of sintering Sintering mechinsms 第十章 烧结过程——10.2烧结过程及机理 Sintering process 1.1 Impact of temperature on sintering body  l－Conductivity ；2－Strength；3－Density Conductivity (Ω-1·cm-3) Temperature (°C) Density (g/cm2) Cu powders Strength (MPa) 第十章 烧结过程——10.2烧结过程及机理 Temperature increases, conductivity, density and strength increase. Conductivity and strength increase before density increases It is difficult to get fully dense samples by normal sintering 第十章 烧结过程——10.2烧结过程及机理 2. Sintering model 第十章 烧结过程——10.2烧结过程及机理 Three stages of sintering Preliminary： Re-arrange of powders，bonding among powders，deform of void Middle： Start to mass transfer，deform of powders Late： Growth of some powders and disappear of some powders 第十章 烧结过程——10.2烧结过程及机理 2 Drive force Decrease of surface energy (Surface tension) Sintering is a irreversible process. 第十章 烧结过程——10.2烧结过程及机理 Because of surface tension, P P0： For spherical surface: （1） For nonspherical surface （2） 第