五氧化二钒纳米颗粒的制备及其电化学性能研究-化学工程与技术专业论文.docx

正极材料。以XRD、SEM、CV和恒流充放电的表征方式对制备样品 进行了性能研究，主要探究不同制备条件(如溶液的pH值、水热温 度、水热时间、填充比以及表面活性剂)对材料性能的影响，得到了最佳的合成条件，最优合成条件为：pH值为3，水热温度为180。C， 水热时间为24h以及填充比为70％。同时，实验表明，表面活性剂的 添加可使V：O，材料的电化学性能进一步提高，在充放电倍率为0．5C 下进行充放电测试，所制备V20，材料的放电比容量和循环性能均高 于未添加表面活性剂的材料。在以上条件下制得的材料表现出了较好的电化学性能，有较好的可逆性和倍率性能以及循环性能，在充放电 倍率为0．1C倍率下进行充放电测试，其首次放电比容可以达到245．89mAh／g。对五氧化二钒进行金属离子掺杂，考察金属离子掺杂的对材料电 化学性能的影响。以XRD、SEM、CV和恒流充放电等表征方法对 制各样品进行了性能研究，其结果表明：金属离子掺杂可以明显地提 高V205材料的电化学性能，在掺杂量为1：0．03下，得到材料的首次 充放电可以高达350．68mAh／g，其值要高于2个Li+嵌入时得到的理 论容量，所制备V：O，材料的倍率性能和循环性能均高于未进行离子掺杂的材料。 关键词：水热法，V205纳米颗粒，电化学性能，铜离子掺杂万方数据ABSTRACTPreparation and electrochemical performanceof V20s nanoparticlesABSTRACTV205 has received extensive attention because of its high theoretical capacity,high discharge platform，convenient synthesis，low cost and SO on．But it also exists some disadvantages，such as poor structure stability,，thepractical application of V205 has been hindered due to low ionic andelectronic conductivity,during the process of charging and discharging，the intercalation／de-intercalation of Li十will lead to the collapse of the layered structure of V205．The nanometer material and metal cation doping caneffectively overcome the disadvantages of V205 materials．This paper prepared pure V205 nanomaterials and metal ion doping of V205 nanomaterials，and characterized the morphology,structure，electrochemical performance and the influence of metal ion doping on the properties of the material．The main work iS summarized as follows：Firetly,a mixed solvent hydrothermal process was used to synthesizenano—structured vanadium oxides．The morphology and crystal structure wereanalyzed using scanning electron microscope(SEM)and x-ray diffraction (XRD)．The electrochemicalperformances were measuered by cyclic voltammogram(cv)and galvanostatic charge—discharge．Mainly to explore the different preparation conditions，composition of solvent，hydrothermal temperature，packing ratio，hydrothermal time．The best preparation conditions were obtained，as shown below：wate