铁基硒化物的结构组成及氧还原活性-材料学专业论文.docx

摘要11AbstractAbstractLow temperature fuel cells include alkaline fuel cell and proton exchange membrane fuel cell．They start up fast with hiIgh specific energy and call be operated at low temperatures．However,they have to use expensive precious platinum based metals as catalysts．Metal selenides exhibit good electrocatalytic activity toward oxygen reduction reaction(ORR)and chemical stability．They are low cost and become candidate materialsfor low temperature fuel cell cathode catalysts．In this work，a series of carbon supported iron based selenides nanocatalysts including carbon supported iron selenide(FeSe2／C)and carbon supported iron cobalt selenide(FeCoSe／C)were rapidly prepared through a simple microwave route．The crystal structures，surface compositions，morphologies andmicrostruetures of catalysts，as well as the degrees in graphitization of carbon supports were studied．The effects of types and adding sequences of carbon supports，types of iron raw materials and solvents，microwave time and selenium／iron(Se／Fe)ratios on the electrocatalytic ORR activities and stabilities were systemtically investigated．Accordingly, the iron based selenide nanocatalysts with good ORR activity and durability were obtained．It was shown that the FeSe2／C catalyst，prepared with ferrous oxalate as an iron source， ethylene glycol and glycerol blend solvent，adding carbon support BP2000 before the microwave at 800 W for 3 min，displayed orthorhombie FeSe2 phase with the averagecrystallite sizes of 44 nnl．The peak potential(耳)and the potential corresponding to ORR(Eoe矾)were 0．733 V and 0．8 1 4 V respectively,in an alkaline medium．The Se／Fe ratios had minor effects on the structures，compositions，morphologies and ORR activities ofFeSez／C nanocatalysts．However,the stabilities were influenced by variations of Se／Fe ratios．Poor ORR activities were obtained for FeSe2／C nanocatalysts in all acidic medium． In the range of Se／Fe=2．0-4．0 studied，the stabilities of FeSe2／C nanocatalysts were improve