特殊纳米组装材料负载贵金属催化剂的设计合成及醇电氧化性能研究-无机化学专业论文.docx

为铂颗粒沉积在钯钴合金表面形成的簇状异质结构，并且该三元金属催化剂对乙醇电氧 化表现出较高活性，稳定性也较强，比单一Pt金属有了显著提高。四、分别以葡萄糖和氯化铜为碳源、铜源，经过水热、高温煅烧、功能化过程，组 装合成了Cu／CuO复合材料，实现了无模板法对花状Cu／CuO的设计合成，并将其应用 于催化剂载体，成功合成了铜／氧化铜复合物负载铂纳米晶催化剂。形貌和结构测试表明， 复合载体材料有铜单质和氧化铜组成，呈现多维放射花状结构。催化剂醇类电氧化测试 结果显示，该催化剂具有很好催化活性和稳定性。总之，本文以催化剂新型复合载体合成应用为研究切入点，制备出具有特殊形貌的 纳米组装材料，并将其负载贵金属催化剂，有效提高了直接醇类燃料电池催化剂的性能， 通过科学的表征方法，系统研究了载体的结构形貌及协同催化效应对催化剂活性的影响 作用。关键词：直接醇类燃料电池，纳米组装材料，Pt基催化剂，Pd基催化剂，电催化氧化n万方数据AB STRACTAs one of the low-temperature fuel eeUs，direct alcohols fuel cells(DAFCs)are environmentally friendly．DAFCs possess some features such as hi曲energy conversion efficiency,clean environmental fueland simple battery Stlllcture，SO that they have great potential for future mainstream energy equipment． However,the performance and efficiency of fuel cell system is essentially governed by the electro‘catalyst which includes metal nanoparticles and support materials．Among the electro-catalyst,the support materials can directly affect the particles size，dispersion,catalytic efficiency and stability of metal nanoparticles catalyst．Therefore，more and more researchers devote themselves to explore new support materials，to improve the utilization rate of noble metal nanoparticles and stability as far as possible through morphology effect,supports effect and synergy．In this paper,we seriously studied the special s帅c嘁s and morphology of support materials，anddesigned as well as synthesized a series of new composite catalysts．To further evaluate the electro-catalytic performance of as-prepared catalysts，the effect of special nano—assembly support materials on electrocatalytic performance of noble metal nanoparticles Was discussed．These studies might provide anew idea and a basic theoretical reference for designing suitable catalyst support materials．The maincontents of this paper were summarized as follows：Firstly,the novel Ag@C nanocables were successfully synthesized and employed as the Pt nanocrystal catalyst support material for the first time．The Pt nanoparticles w