用于白光led的（卤）硼酸盐荧光粉制备及发光性质研究-无机化学专业论文.docx

AbstractWhite light—emitting diodes(LEDs)are considered as the new generation of illumination source owing to their numerous advantages such as long lifetime，energy saving，mercury—free，etc．Achieved bycombination of a blue emitting diode with a yellow phosphor Y3AIs012： Ce3+is best known which was Nbficated firstly by Nichia Chemical Co． Y3A15012：Ce3+has a high quantum efficiency and high thermal stability, however，the lack of red—emitting component leads to a low color rendering index(CRI)of the white LEDs(80)．There are several ways to obtain a high CRI value，for example，the combination of a near-UV chip with tricolor phosphors，or a blue—emitting chip combined with green／yellow and red phosphors with strong absorption in the near—UV and／or blue region．Therefore，it is very important to search for highefficiency phosphor that has a strong absorption in the near UV or blue light region．In this thesis，Cas(B03)3F was selected as the host．The luminescentproperties of phosphors single—doped with Ce3+，CO—doped with Ce3+，Tb3+， and CO—doped with Ce3+，RE3+，Mn2+were studied in detail．The relationships between the properties such as PLE and PL，energy transfer and crystal structure were analyzed，and the following results were obtained：III万方数据Cas(B03)3F：Ce”phosphors exhibited purple—blue light emission peaking at 3 92 nm，with a strongest excitation band at 3 60 nlTl，which belongs to the Ce3+in Ca(2、)site．2)In Cas(B03)3F：Ce3+，Tb3+phosphors，the excitation energy of Ce3+can be transferred to Tb3+effectively，the CO—doping of Tb3+leads the appearance of green emision of Ce3+in Ca(1、)site．3)In Ca5(B03)3F：Ce3+，RE3+，Mn2+phosphors，the energy of Ce3+ could not transferred to Mn2+effectively,while the introduction of RE3+ enhances the emitting of Mn2+significantly．The key factor that leads tothe enhancement of Mn2+emission is the increase the amount of Mn2+onCa(2、)site with the introduction of RE3+．4)Eu3+can’t be reduced in Ca5(B03)3F under the reducing atmosphere，but can be reduced in Sr382