铝合金硼酸―硫酸阳极氧化膜结构及耐蚀性研究-材料物理与化学专业论文.docx

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2018-05-05 发布于上海
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铝合金硼酸―硫酸阳极氧化膜结构及耐蚀性研究-材料物理与化学专业论文.docx

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铝合金硼酸―硫酸阳极氧化膜结构及耐蚀性研究-材料物理与化学专业论文

AbstractBoric-sulfuricacidanodic(BSAA)filmhasexcellent corrosionresistance,overcomestheshortcomingofpoorfatiguepropertyofcommonsulfuricacidanodicfilm,andhaslessenvironmentalpollution.Soithasbroadapplicationprospects.Inthispaper,theBSAAtechniquesofnew2×××、7×××aluminumalloyswereoptimized.The impactsofboricacidon thestructureandcorrosionresistanceofanodicfilmsweremainlyresearched bySEM、AFM、SKPand EIS.Furthermore,a newgreensealing techniqueforBSAAfilmusingceriumsaltconversionsolutionwasalsostudied.Theresultsshowed:Theuniformanodicfilmsof3~4μm canbeobtainedwhen2×××aluminumalloywasanodizedat15~18V,7×××aluminumalloywasanodizedat15Vfor25mininanodicelectrolyte(50g/LH2SO4+8g/LH3BO3)at24~26℃.Theadhesionbetweenfilmsandcoatingcanachieve0level.Thefilmscanbear504hsaltspraytestwhentheyweresealedbydiluteCrO3solution.Themicrostructureof filmissimilartoclassicalsulfuricacidanodicfilm,whichisporousanodicfilm.Buttheporestructureisnotobviousasthediameter ofporewassmaller. The main elementsofthe filmareAl、O、S,simultaneouslythecontentofOaremuchhigherthanthestoichiometriccontentofAl2O3, whichindicatedthatthefilmalsomayexistacertainamountofhydratedAl2O3.IntheBSAAsystem,thecontentofsulfuricacidhasgreatestinfluenceontheweightandcorrosionresistanceofthefilm,andtheboricacidmainlyaffectsthestructureoftheporouslayer.Itishelpfultoreducethesolubilityoftheelectrolytewhenaddingappropriateamountofboricacidtoelectrolyte,whichisbeneficialtoimprovetheappearanceoffilmandthestructureofporouslayer, madethefilmbecomemoreuniform、compact,theporebecomesmaller,thecorrosionresistanceincrease.Itshowedthattheresistanceofporouslayer(Rp)increased,thecapacitance(CPEp)decreased,thesurfacepotentialmovedpositively,theworkfunctionforelectroniceffusionraised.Whereas, thehigh contentofboricacidwillresultinthepore sizeoffilm becomelarger,theresistancereduced,theworkfunctionfell,thecorrosionresistancedecreased.IntheBSAAprocess,thechangeofanodicvoltageorelectrolytetemperaturecanleadtothevarietiesofanodiccurrentdensityandelectr