膨胀阻燃聚乳酸复合材料的制备、性能和阻燃机理研究-安全技术及工程专业论文.docx

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2018-05-05 发布于上海
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膨胀阻燃聚乳酸复合材料的制备、性能和阻燃机理研究-安全技术及工程专业论文.docx

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膨胀阻燃聚乳酸复合材料的制备、性能和阻燃机理研究-安全技术及工程专业论文

ABSTRACTPolylactide(PLA)isabiodegradablepolymerderivedfromrenewableagriculturalproducts.Theexcellentmechanicalandbiocompatibilitypropertieshavemadepolylactidereplacepolyolefinstosomeextent.However,thepoorfireresistance,especiallythedrippingtendencyduringthecombustionlimitedtheapplicationof polylactide,somodificationforflameretardancyisnecessary.Basedontheinvestigationofalargeamountofliteraturesabouttheproperties,theflameretardantdevelopmentofpolylactideandtheuseofcarbonnanotubesandPOSSontheflameretardantstudyofpolymers,inthisdissertation,intumescentflameretardant(IFR) havebeenusedtoimpartPLAwithflameretardancy,theflamepropertiesand mechanismhavebeenstudied.NewintumescenttechnologysuchmicrocapsulationandnewintumescentflameretardanthavebeenusedtoflameresistantofPLAstudy. Inaddition,Trisilanolisobutyl-POSS(TPOSS)andmulti-walledcarbonnanotubes (MWNTs)havebeenused,thesynergisticeffectonthethermalpropertiesandflameretardancyofPLA/IFRcompositeshavebeenstudied.Thisdissertationiscomposedofsixparts:CharringagentsPEPAandODOPMhavebeenpreparedthecombinationof charringagentsandMPhavebeenusedasintumescentflameretardantsforPLA. FromtheresultsofLOI,UL94test,itcanbefoundthatflameretardantPLA compositewiththesuitablecontentofMPandODOPMhasabetterflameretardantpropertiesandahigherfiresafety.PLA/MP/PEPAhasahighLOIvalueandpasses theUL94V0test,nodriphasbeenseenduringthecombustion,theadditionofPU canimprovetheimpactstrengthandtensilestrengthofPLA/MP/PEPAcomposites,morestablecharhasbeenseenaftercombustionwiththePU.PLA/IFRcompositeswhichtheacidsourceisDOPO-BQ,thegassourceisTGICandthecarbonsourceisPLAhavebeenprepared.BytheadditionofIFR, higher LOI value has been achieved; UL94 V0 rate has been reached; PHRR has been reducedcomparedwith purepolylactide.TGAresultsshowthatPLA/IFRcompositeshavehigherthermalstabilityandcharproduction.Theanalysisofthecharaftercombustionshowsthatmoreimpactofcharhasachievedwhichcanimprovethefiresafetyofthematerial.NewIFRBTOCPMwhichcombinedwithacidsource,gas sourceandc