乌梁素海重金属环境地球化学特征及其存在形态数值模拟研究-农业水土工程专业论文.docx

the heavy metal sources are the parent rocks, industrial pollution, agricu ltural non-point-source pollution and atmospheric deposition. The chemical speciation of Cu, Zn, Pb, Cr, Cd, Hg, and As in sediment was analyzed based on the European Communities Bureau of Reference (BCR) fractionation method. The correlation of the chemical speciation and biological activity among these metals were analyzed based on their chemical and physical characteristics, and the ratio of secondary phase to primary phase (KRSP) was employed to assess the heavy metal pollution in sediments.The results show that i) total concentration is the most important factor affecting the residual fraction;ii) organic matter, pH, and salinity are the primary factors affecting the acid extractability and the adsorption of sulfur compound by organic matter; iii) total nitrogen and total phosphorus are the main factors affecting the adsorption of sulfur compound on organic matter. Iiii) based on the total concentration and bioavailability, Cd is the most risk metal, followed by Hg. So, more attention should be paid to Cd and Hg pollution in WL.As different chemical species in water have different toxity to organism, the speciation of the studied metals in WL was analyzed with the PHREEQC model. T he HREEQC database for these heavy metals was established with HSC Chemistry v5.0 software. The chemical species of Hg, Cr, As, Cu, Zn, Pb and Cd in water solution werefound from literature. The results indicate that CuCl2-, CuCl32-, CuCO3, Cu(OH)2, Zn2+,Zn (OH)2, ZnCO3, ZnSO4, PbCO3, PbOH+, Pb(CO3)22-, Cr(OH)3, Cr(OH)2+, CdCl+, Cd2+,CdSO4, CdCl2, Hg(OH)2, HgCl3-, HgCl2, HAsO42- , and H3AsO3 are the dominant species in WL. As HgCl2 is very toxic and mercury pollution did not meet the national standard, Hg pollution should be paid more attention. With the change of seasonal weather, the temperature, redox, and pH of the lake will be changed. The impact of temperature, redox and pH on the heavy metal species in W