碱金属钽酸盐微晶的可控生长及表征-材料学专业论文.docx

AbstractResource crisis and environmental protection are two global issues in the 21st century. Tantalates have attracted attention for its high photocatalytic properties. Its photocatalytic properties not only can prepare hydrogen to save resources but also can degrade organic to protect environment.Products with different morphology and structure can be prepared by different methods. In this paper, a series of alkali tantalates microcrystals had been successful synthesized by molten-salt, hydrothermal and state reaction methods. Structures, components and morphology were confirmed by Thermogravimetric Analysis (TG), X-ray Diffraction (XRD), Scanning Electron Microscope (SEM), Fourier Transform Infrared Spectroscopy (FTIR).It was shown that the method of molten-salt can significantly reduce the reaction time and temperature, and a more uniform appearance was observed. The effects of the reaction temperatures, the ratio of mass and the surfactants to the synthesis of alkali tantalates microcrystal were studied. The best reaction process was 10:1 in ratio of mass, and 950 °C for 4h, with doping PEG. Er doping of alkali tantalates can significantly reduce the reaction temperature and the best amount of Er was 2 %.The alkali tantalates nanocrystals were prepared by the method of hydrothermal. The effects of the reaction temperature and time, the alkali concentration and doping of graphene oxide (GO) to the synthesis of alkali tantalates nanocrystals were studied and thebest reaction process was 140 °C for 12 h，with doping Go.Fresh tantalum hydroxides as raw materials can reduce the reaction temperature with the method of state reaction. Mixing sodium and tantalum hydroxides together and heating at a low temperature (675 oC) produced NaTaO3 microcrystal.Keywords: Alkali Tantalates; microcrystal; Molten-salt; Hydrothermal目录摘 要...................................................................................................................................................