有机光伏器件的界面电子结构及其电子复合与产生过程的分析-凝聚态物理专业论文.docxVIP

Abstract StudiesoninterfaceelectronicsofchargegenerationandrecombinationinterfacesinorganicphotovoltaicscommonlyusedelectrondonormaterialsinOPV.Westudiedtheinterfaceelectronic structuresofHAT-CNandtheactivematerialsinpolymeisolarcell.Andwefindthat theinterfaceenergylevelalignmentfacilitatestheholeextractionfromP3HTtothe anode.WealsestudiedtheinterfaceelectronicofNPBandP3HT:PCBM.Butwefound nointerfaceenergybendingthatcanfacilitatetheholetransportformP3HTtothe anode.N-typedoping ofelectrontransportmaterial.Westudiedthe energylevels evolutionofAlq3dopedwithdifferentconcentrationofCs2CO3.Theresultsshowthat Cs2CO3isanefficientn-typedopantandithelpstoincreasethedensityofelectrons. The electroninjectionbarrierisreducedandelectronconductivityisimproved by dopingeffect.Keywords:tandemorganicsolarcells,HAT-CN,holeinjection,holeextraction, interface electronicstructure,Cs2CO3doping.WrittenbyLiJianSupervisedbyProf.YanqingLiand JianxinTangIV目录第一章绪论····················································································11.1引言···················································································11.2 有机光伏器件的发展历程························································21.2.1 有机光伏器件的发展历史·················································21.2.2 有机光伏的产业化现状····················································51.3 有机光伏器件的工作原理························································51.3.1 光电转换原理及模型·······················································51.3.2 有机光伏器件的结构·······················································61.3.3 有机光伏器件的主要材料·················································91.3.4 有机光伏器件的制备方法················································101.3.5 有机光伏器件的表征参数················································111.4 有机光伏器件目前的主要挑战及可能的解决方法··························121.5本论文的主要工作································································131.6参考文献············································································13第二章有机半导体界面