聚乳酸聚（已二酸-对苯二甲酸丁二酯）共混物材料的制备与性能研究-高分子化学与物理专业论文.docx

PLA/PBAT共混物体系的非等温结晶过程。TBT的加入对PLA的成核机理和晶体生长规律影响不大，晶体生长方式均为二维盘状生长和三维球晶生长并存；此外，还利用Vyazovkin的方法求得PLA/PBAT共混物结晶活化能与温度之间的关系。关键词：聚乳酸，聚已二酸-对苯二甲酸丁二酯，共混物，性能，结晶动力学PreparationandPropertiesofBiodegradablePoly(lacticacid)/Poly(butyleneadipate-co-terephthalate)BlendsAbstractPoly(lacticacid)(PLA),asabiodegradablethermoplastic,hasattractedgreatattentionduetoitshighmodulus,tensilestrengthandcommercialavailability.However,thefurtherdevelopmentandpracticalapplicationsofPLAisrestrictedbyitsbrittleness.Poly(butyleneadipate-co-terephthalate)(PBAT)isabiodegradablealiphatic–aromaticcopolyesterwithhightoughnesssynthesizedfromadipicacid,terephthalicacidandbutyleneglycol.Poly(lacticacid)/Poly(butyleneadipate-co-terephthalate)blendsarepreparedbymelt-extrusion,andthemechanicalproperties,morphology,rheologicalbehaviorandcrystallizationpropertiesoftheblendsareinvestigatedbydynamicalmechanicalanalysis(DMA),scanning electronmicroscopy(SEM),capillaryrheometer,polarizingmicroscopy(POM) and differentialscanningcalorimeter(DSC).Themajorresultsaresummerizedasfollowing:ThemechanicalpropertiesresultsdemonstratedthattheelongationatbreakofblendsimprovedremarkablycomparedtopurePLAandthemaximum(298%)wasachievedat0.5%TBTcontent, atwhichtheimpactstrengthofblendswasalso increasedby 76%.SEMimagesshowedthatthecompatibilityobetweenPLAandPBATissignificantlyimprovedwiththeincorporationofTBT.DynamicmechanicalanalysisdemonstratedtheoccurrenceoftheglasstransitiontemperatureforbothPBATandPLA,indicatingthatPLAand PBATareincompatible.TherheologicalpropertiesresultsrevealedthatbothPLAanditsblendsarepseudo-plasticityfluid,anddisplayedobviousshear-thinningphenomenon.PLAand itsblendsmeltshaverelativelylowviscousflowactivationenergy,whichindicatedPLAmeltshaslowtemperaturesensitivityandisbeneficialtothecontrolofprocessingconditions.Thepolarizedopticalmicroscopy(POM)micrographsshowedthatthespherulitesizehasagreatdependenceonthecrystallizationtemperatureandTBTloading.ThespherulitesofthePLA/PBATblendsbecomesmallerwiththeadditionofT