含银多金属硫化矿选矿试验研究.docVIP

某含银多金属硫化矿选矿试验研究( 邱廷省1,丁声强1,张宝红1,伍红强2,杨云1,张德文1 (1.江西理工大学资源与环境工程学院,江西 赣州 341000; 2.中钢集团马鞍山矿山研究院Experiment Study On Mineral Processing Of A Silver Multi-Metal Sulfide Ore Qiu Tingsheng1, Ding Shengqiang1, Zhang Baohong1, Wu Hongqiang2, Yang Yun1, Zhang Dewen1 (1.Faculty of Resource and Environmental Engineering , Jiangxi University of Science and Technology , Ganzhou 341000,China; 2.Maanshan Institute of Mining Research , Sino-Steel Group , Maanshan 243000,China) Abstract: An experimental research on mineral processing of a silver-containing polymetallic sulfide ore was studied. The mineral processing study showed that the ore has complex mineral components, minerals symbiotic closely. Using copper-lead-zinc preferential flotation processing : Z-200 acted as copper preferential flotation collector, QF-11 as lead preferential flotation collector, CuSO4 as zinc activator, butyl xanthate as zinc collector. The closed-circuit tests showed that the copper concentrate of 20.02% Cu with a recovery rate of 69.30%, containing silver 8150.32g/t, silver recovery rate of 55.01% was obtained, the lead concentrate of 55.01% Pb with a recovery rate of 81.86%, containing silver 2400g/t, silver recovery rate of 37.80%, the zinc concentrate of 50.56% Zn with a recovery rate of 81.28%. QF-11 has good lead preferential flotation in low alkali, using QF-11 as the lead collector in the election of lead job, it can not only avoid the use of a large number of lime, but also concentrate the precious metal silver in the lead concentrate , it can improve the recovery rate of associated silver. Key words: Multi-Metal sulfide ore; Preferential floatation; QF-11; Lead flotation in low alkali; Associated silver 引言 复杂多金属硫化矿石中常伴生贵金属金、银，伴生银储量分布占全国银总储量的70.3%，且大部分伴生在铅锌矿和铜铅锌矿中，回收硫化矿中的伴生金、银具有重要价值。在处理含贵金属金银矿时，常采用浮选法使金、银富集在铜、铅精矿中[1-2]，根据矿石性质可采用不同的选矿工艺[3]。许多选矿工艺为了选别主金属矿物，在浮选时，通过添加大量石灰来造成高碱环境，而伴生金、银矿物对矿浆pH值变化敏感[4]，金、银在高碱矿浆中受到抑制变为亲水，降低了金、银回收率。选用低碱度下对矿物选择性捕收能力强的捕收剂[5]，不仅可以减少pH调整剂的用量，也有利于伴生金、银在精矿中富集，提高伴生金、银的回收。