纳米复合物修饰电极的制备及用于有机污染物检测研究-环境工程专业论文.docxVIP

-6-6-4I(μA)=2.840+0.07744C(μM)，其中R=0.9982，检出限为3×10PP mol/L；对CC而言，在8×10PP~4×10PPmol/L，其线性方程为I(μA)=0.08636+0.1157C(μM)，R=0.9997，检出限为2.7×10PP mol/L。结果表明，通过电化学还原方法成功的将氧化石墨还-6原为石墨烯，ERG/Zn-CrLDHs/GCE修饰电极能以较宽的电位(101mV)将对苯二 酚和邻苯二酚区分开来并实现同时灵敏检测。关键词：纳米复合材料，修饰电极，有机污染物，检测AbstractAtpresent,detectionandmonitoringoforganicpollutantinwaterhaveattractedpeople’sattention. Because electrochemicalanalysis has advantageof rapid, simple tooperateandeconomic,itisappliedtoanalysethepollutantsinthethewater.Butthemodifiedelectrodeswasrequirestobesensitiveandselective,andcanreduceoverpotentialsofanalytes,whichhasbroughtnewchallengetotheelectrodemodifition.Nanocompositesmaterialpresentpropertiesbothofinorganicandorganicmaterial,whichhas theunique electronic,optical andcatalytic properties.Compositesmaterialcanmakeuseofsynergisticeffectbetweenmaterials,producingunexpectedeffectwhichcansolvetheproblemsofelectrodemodifition.Therefore,nanocompositesmaterialcanbeappliedtomodifyelectrode,detectingorganicpollutants.Thispaperhavedesignedandpreparedtwoelectrodesmodifiedwithnanocompositesthathavehighelectrochemicalcatalyticperformence,aimingatthedetectionoforganicpollutantsinwater.Themorphologyofmodifiedelectrodeswerecharacterizedbyusingscanningelectronmicroscopy(SEM)technology.Themodifiedelectrodesdetectedorganicpollutantswithdifferentconditions,andtherelatedresearchincludes:-3-6-6-5Anovelgoldnanoparticles(GNPs)andcarbonnanotubes(CNTs)hybridnanocomposite modifiedglassycarbonelectrode(GNPs/CNTs/GCE)was preparedby usingpotentialstepmethodinthesolutioncontainingthecarboxylatedCNTsandHAuClB4B.Themodifiedelectrodewascharacterizedbycyclicvoltammetry(CV), electrochemicalimpedancespectra(EIS)andscanningelectronmicroscopy(SEM). TheelectrochemicaloxidationbehaviorofHCatecholH(CC)T TandBisphenolA(BPA)on themodifiedelectrodewasinvestigated.TheresultsshowedthattheGNPs/CNTs/GCEhasastrongelectrocatalyticactiononCCandBPAinphosphatebuffersolution(PBS)ofpH7.0.Theexperimentalparameters,whichinfluencethe