对称性与光谱学-第二章-1.pptVIP

Symmetry point groups C1 - only E Cs - E, ? Ci - E, I 3.Dihedral groups adding a C2 perpendicular to the Cn requires that there must be n C2 axes perpendicular to the Cn Dn - Cn + n?C2 axes (molecules in this group must have a zero dipole moment and be optically active Dnh - Dn + ?h Dnd - Dn + ?v. The ?v operations will bisect the adjacent ?C2 axes High symmetry molecules It is best to learn to recognize molecules of particularly high symmetry Two types of high symmetry are observed: linear molecules such as HCCH and HCN tetrahedral and octahedral molecules 6. Platonic solids Rotational subgr