OLED 磷光材料进展-kido综述文献（上半部分）.ppt

Outline Introduction Blue PhOLEDs HIHT Materials ETHB Materials Hosts Phosphorescent Dyes Green PhOLEDs Red PhOLEDs White PhOLEDs Introduction Electro-phosphorescent Introduction Introduction Introduction Blue PhOLEDs are hard to obtain: Content Blue PhOLEDs HIHT Materials ETHB Materials Hosts Phosphorescent Dyes HI HT materials HI HT materials PEDOT:PSS HI HT materials HI HT materials ET HB Materials Generally, hole mobility is much higher than electron mobility ET HB Materials ET HB Materials ET HB Materials Hosts Phosphorescent dyes have relatively long excited-state lifetimes Host-Guest system to avoid triplet-triplet annihilation. Hosts-Carbazole Best candidates for blue phosphorescent host materials Hosts-Carbazole Hosts-Carbazole Hosts-Carbazole Hosts-Carbazole Hosts-Aryl Silane Hosts-Aryl Silane Hosts-Phosphine Oxide Hosts-Phosphine Oxide Phosphorescent Dyes NTSC: standard blue (0.14,0.08) Phosphorescent Dyes Phosphorescent Dyes A) Introduce electron-withdrawing groups to lower HOMO B) More electron accepting ancillary ligand to lower t2g C) Electron-donating groups to the pyridine D) Replace pyridine ring to N-heterocyclic to higher LUMO E) Using a strong σ-donating ligand to lower t2g Phosphorescent Dyes A:Introduce electron-withdrawing groups to lower HOMO Phosphorescent Dyes B:Changing the ancillary ligand to be more electron accepting Phosphorescent Dyes C:Introduce electron-donating groups to pyridine ring Phosphorescent Dyes D:Replacing the pyridine ring to N-heterocyclic ligand Phosphorescent Dyes E:Using strong donating ligand Summary A) Introduce electron-withdrawing groups to lower HOMO B) More electron accepting ancillary ligand to lower t2g C) Electron-donating groups to the pyridine D) Replace pyridine ring to N-heterocyclic to higher LUMO E) Using a strong σ-donating ligand to lower t2g The Deeper the Harder! 452nm (0.18,0.13) 451nm/471nm 0.62 C 414nm 449nm/479nm D 395nm (0.17,0.06) 0.002 (0.16,0.13) E Recent Progresses on Materials