bola型聚氨酯表面活性剂的合成及溶液性能分析word格式论文.docxVIP

逐渐减小。2. 用乌氏粘度计测定了 Bola 型聚氨酯表面活性剂在不同浓度下的溶液粘度行为。 实验结果表明：当表面活性剂的浓度在临界胶束浓度以上时，溶液的相对粘度与浓度的 关系和传统的小分子表面活性剂相似，随着表面活性剂浓度的降低，溶液的相对粘度也 逐渐降低，二者呈线性关系；当表面活性剂的浓度在临界胶束浓度附近时，随着表面活 性剂浓度的降低，粘度会出现先降低然后又升高的现象；当表面活性剂的浓度在临界胶 束浓度以下时，溶液的相对粘度与浓度的关系曲线出现向上的偏离，即随着表面活性剂 浓度的降低，溶液的相对粘度逐渐增加。实验结果说明该类表面活性剂溶液的粘度在临 界胶束浓度附近和小于临界胶束浓度时和普通的小分子表面活性剂不一致，会出现反常 现象。本论文分别用临界浓度的观点和吸附观点解释了这种反常现象。3. 利用浊度法研究了该类表面活性剂对甲苯的增溶作用，发现对甲苯的增容量好于 传统的表面活性剂 OP-10，随着亲水链段的增加，增溶能力逐渐减小，并建立了该类表 面活性剂对甲苯可能的增溶模型。4. 本课题还研究了新合成的表面活性剂的部分其它性能：乳化性能好于传统的表面 活性剂 OP-10；浊点随着亲水链段的增加逐渐升高，分别为 86 ℃、92 ℃、95 ℃。关键词Bola 型表面活性剂，聚氨酯，溶液性能，粘度Study on the Synthesis and Solution Properties of Bola Polyurethane SurfactantsAbstractThe chemical structure consists of two hydrophilic groups connecting with a hydrophobic chain is Bola surfactant. Due to the two polar hydrophilic head groups, it has good solubility in water and the micelles has good stability in water. Bola surfactant can be used in some special field (such as drug delivery, simulation of biological membrane, etc), has attracted the attention of scholars at home and abroad.Based on the above advantages, three new Bola polyurethane surfacents with different length of hydrophilic chain were synthesized with the advantage of Bola surfactant, polymeric surfactants and polyurethane surfactant. In the synthesis process, by changing water and oil chain segment ratio, three Bola type polyurethane surfactants was synthesized for the firsttime and the structure of products have been characterized by IR and 1H NMR etc. Focuse onboth the Bola polyurethane surfactant solution properties. In addition, the solubilization ability of the Bola polyurethane surfactants were studied.The experimental results are as follows:⒈ This suspension loop method is used to test the surface tension of the new Bola polyurethane surfactant under different conditions and to reflect the critical micelle concentration by surface tension. The experimental results show that:⑴ In 25 oC secondary distilled water, as the hydrophili