cuomox介孔cezro2催化剂用于h2中co优先氧化的分析word格式论文.docxVIP

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cuomox介孔cezro2催化剂用于h2中co优先氧化的分析word格式论文.docx

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cuomox介孔cezro2催化剂用于h2中co优先氧化的分析word格式论文

AbstractAstheconceptofthesustainabledevelopmentisputforward,peoplegradually realizetheimportanceofenergyandenvironmentalproblems.Thehydrogen, whichis ahighefficiencyandnearzeroemissionofenergysource,becameoneofthemost promisingfuelsatpresent.Fossilfuelswillreleaseplentyofgreenhousegasand wastegaswhentheyareburning.Protonexchangemembranefuelcell(PEMFC)is oneofthemosteffectiveandimportantformsofhydrogen.Hydrogen-richgasisthe fuelof thefuelcell,becauseitcontainsatraceofCOandcouldresultinPtelectrode poisoning.Sotheservicelifeoffuelcellwillbereduced.Themosteffectivemethod ofselectiveoxidationis removingCOfrom hydrogen-richgas.Theresearch of non-noblemetalcatalystsforCuO/CeO2ismoreextensivethanothersinselective oxidationcatalyst.Becauseitshows wellselectivecatalyticoxidation activityofCO.Thestudyincludesthreekindsofpreparationmethods,suchasthewaterhot-dip method,coprecipitation-dippingmethodandcitricacidcomplexing-dippingmethod, andmakescatalystofCuO/m-CeO2-ZrO2.Inaddition,theinfluenceofprecipitating agentcontent,CuOload,doublemetalloadanddoublemetalloadonperformanceof catalystforselectiveoxidationofCOisinvestigated.Atlast,wegetsomevaluable researchresults.ThestudieshavefoundthatacatalystofCuO/m-CeO2-ZrO2increasesthe specificsurfaceareaofcatalystsandincreasesthedispersionofCuOby co-precipitation-impregnationmethod;whenNaOHandNa2CO3areusedas precipitant,thedispersionofCuOisimprovedina certainextent,thereduction temperatureofCuOisreduced,theapertureofacatalystisreduced,andspecific surfaceareaofcatalystsisincreased.ThesuitablecapacityofCuOimprovesthe adsorptionofCOonCu1+interfaceandreleasesthereactivityofoxygenionsfrom carriers;theappropriatemetal andCuOareloadedtoCeO2-ZrO2,thesintering phenomenaofcatalystisimprovedbythesynergyofthetwometals;asa consequence,theoxidationandreductiontemperatureofsolidsolutionisreduced, specificsurfaceareaofcatalysts,capacityofoxygenstorage,restoringabilityinlow temperatureandthermal stabilityareincreased. Toimprovethecatalyticperformance.Thes