d001树脂去除铅离子的静态和动态特性分析word格式论文.docxVIP

AbstractLead is hard to biodegradable, easily enriched in the food chain, having caused great threat to the natural ecological environment and human health. In order to solve the lead pollution, effective techniques and methods have been exploring to remove lead around the world. Among them, the ion exchange technology with high adsorption capacity is to be the main direction of heavy metal treatment. D001 resin is cheap and commercial produced, but less used in heavy metal removal. The purpose of this work was to evaluate the potential of lead removal in aqueous solution by D001 resin.In the static experiments, we first investigate the single factor influence on D001 resin to remove lead, such as the initial pH, solid-liquid ratio, initial lead ions concentration, reaction time and reaction temperature. And on this basis, the optimum reaction conditions were determined. Then we explored the effect of other metal ions on the lead removal by D001 resin and the regeneration of D001 resin. The experimental results show that, a sorbent amount 0.04g in 80ml aqueous solutions for 200mg/L Pb(II), contact time 300min, at pH 3, the maximum removal efficiency reaches 93%, and the corresponding adsorption capability is 360mg/g. In the competitive adsorption of binarysystem, the presence of Al3+ has obvious negative effect on Pb2+ removal by D001 resin.In order to investigate the kinetics of adsorption, three kinetic models, Pseudo first order equation. Pseudo second order equation and intra-particle diffusion process were employed. We found that the process of D001 resin to remove lead conforms to the pseudo first order kinetics model. Isothermal experimental data are evaluated with Langmuir and Freundlich isotherms, the results show that the Langmuir isotherm fitting is more appropriate. The thermodynamic parameters of the adsorption for lead ions, ?H0,?S0, ?G0, indicated the adsorption process is spontaneous and endothermic.In the dynamic experiments, the performance of the