eu3 sr2 共掺杂纳米二氧化硅发光材料的制备word格式论文.docx

的谱线的强度最大，其颜色为红色，是 Eu3+的特征谱。Eu3+离子掺杂纳米二氧化 硅发光材料中可见光区的 580-590nm 、616nm、660nm、710nm 这些发光峰分别 是由 5D0-7FJ（J=0，1，2，3，4）能级跃迁引起。考察了 Eu3+离子掺杂的不同浓 度对材料发光性能的影响，随着 Eu3+离子掺杂浓度的提高，发射光的强度先增强 后减弱；当掺杂浓度为 0.5%时，发射光的强度较强。Sr2+单掺杂纳米二氧化硅材料的发射光谱出现了位于 343nm 和 670-690nm 的 发射峰。将其激发光谱和发射光谱与未掺杂纳米二氧化硅材料的激发光谱和发射光谱进行比较，可以发现光谱极其相似；Sr2+的加入并未引起纳米二氧化硅材料 发光峰的位置改变，只是发光峰强度增强，仅起到了加强作用。Eu3+-Sr2+共掺杂纳米二氧化硅发光材料的发射光谱中主要存在有 4 个发射 峰，分别位于 409nm、470nm、580-590nm 、616nm 处。研究表明，不仅 Sr2+离子的加入对材料的发光性能有很大的影响，并且加入的量不同对其影响不同。与 只掺杂 Eu3+离子的纳米二氧化硅发光材料相比较，Sr2+掺杂浓度≤0.5%时发射峰 位置几乎未发生变化，只是发光强度有不同程度的增强；但是在 0.5%＜Sr2+掺杂 浓度≤1.0%时，出现了位于 409nm 处的属于 Eu2+的特征发射峰，说明随着 Sr2+的加入使材料中一部分的 Eu3+离子转换成了 Eu2+。考察了不同温度对材料发光 性能的影响，随着温度的升高，发射峰位置没有改变，只是强度发生了变化， 409nm 处的发射峰强度随之减弱，616nm 处的发射峰强度随之增强。关键词：Eu3+-Sr2+共掺杂 发光性能 纳米二氧化硅材料 溶胶-凝胶法Preparation and Luminescent Properties of Eu3+-Sr 2+co-doped nano-silica materialsIntroduction of the author: Wang Xiaoyan, female ,was born in October, 1984 whose tutor was Professor Lin Jinhui. She graduated from Chengdu University of Technology in mineral materials major and was granted the Master Degree in June, 2010.AbstractBecause of the special electron shell structure, the rare earth- doped luminescence materials has been provide with outstanding luminescence properties than the other type luminescence materials.The abundant and cheap Eu3+ was selected as the activated dose of nano-silica material, and the materials were luminous. In the process of preparation of Eu3+ doped nano-silica, a definite amount of Sr2+ was added . The results showed that Eu3+-Sr2+ co-doped nano-silica were not only improved the luminescence properties of raw materials, and also produced new luminescence centers. It was very useful to making cheaper and more practical luminescent materials.In this paper with TEOS as precursor, ethanol as solvent, nothing doped , rare earth Eu3+ single-doped, Sr2+ single-doped and Eu3+-Sr2+ co-doped nano-silica luminescence materials were prepared by sol - gel method. Using XRD, SEM, DSC-TG, FTIR, PL, an